%nprocshared=24
%mem=41GB
#p opt freq=noraman b3lyp 6-31g(d) scrf=(pcm,solvent=n,n-dimethylformamide) nosymm empiricaldispersion=gd3 scf=(xqc,maxcyc=1024)

Opt freq

0 1
 C                  0.81390693    0.57050009   -0.80218703
 C                  1.51549181    1.63998618   -1.61757102
 C                  0.83545170    2.60627611   -2.33420400
 C                 -0.66743130    2.64925694   -2.37259700
 C                 -1.36114519    1.66343386   -1.77300601
 C                 -0.62338407    0.58148093   -0.95054303
 C                  1.46222908   -0.73726483   -1.27031504
 C                  2.59762705   -0.44469169   -2.23154604
 C                  2.63408488    1.01511932   -2.44548602
 C                  3.05490083    1.49213138   -3.65858802
 C                  1.28425964    3.15271318   -3.67376000
 C                 -1.11894437    3.22949791   -3.68148399
 C                 -2.23569332    2.75810679   -4.29153300
 C                 -2.99797819    1.65420769   -3.65698301
 C                 -2.56957113    1.13084473   -2.47472502
 C                 -2.60292596   -0.32113028   -2.25672604
 C                 -1.41052092   -0.67577615   -1.41809904
 C                 -0.77103179   -1.82649408   -1.69480105
 C                  0.73028521   -1.84377691   -1.67049606
 C                  2.98458714   -1.28196463   -3.24509305
 C                  2.23112128   -2.51714771   -3.52491806
 C                  1.13832532   -2.78536585   -2.78201807
 C                 -0.08208862   -3.34064898   -3.44680607
 C                 -1.26415669   -2.74728912   -2.77756706
 C                 -2.36319173   -2.42643324   -3.50797806
 C                 -3.06452987   -1.14805132   -3.23509804
 C                 -3.53682694   -0.58529836   -4.53790504
 C                 -3.50347909    0.75729465   -4.74017502
 C                  0.08825559    3.54271705   -4.48454199
 C                 -1.42670109    0.77551592   -7.86129202
 C                 -0.71335022    1.91206500   -7.61013601
 C                  0.78739378    1.87315417   -7.61503001
 C                  1.44058691    0.70390225   -7.87236003
 C                  0.65565206   -0.54833284   -8.14717504
 C                 -1.48710482   -1.62720209   -7.49913405
 C                 -2.68670889   -1.02586224   -6.82334804
 C                 -2.64925206    0.45937577   -7.04765503
 C                 -3.04184315    1.30819372   -6.05495302
 C                 -2.25633030    2.55327080   -5.77634400
 C                 -1.14919533    2.84166894   -6.51418500
 C                  1.27473068    2.77791321   -6.51974000
 C                  2.36330072    2.42822633   -5.78464401
 C                  3.07747286    1.15101241   -6.06609902
 C                  2.64593796    0.32647538   -7.06263503
 C                  2.60909113   -1.15623363   -6.84036105
 C                  1.38031919   -1.69889276   -7.51106605
 C                  0.67327630   -2.70884585   -6.92559007
 C                 -0.82819670   -2.67205102   -6.91972706
 C                 -3.11338983   -1.52284130   -5.62721905
 C                 -2.38678070   -2.66793322   -4.98832306
 C                 -1.30091764   -3.21409109   -5.60180407
 C                 -0.09175660   -3.57343596   -4.79184908
 C                  1.12465437   -3.26934981   -5.60928307
 C                  2.23465431   -2.77009069   -5.00343107
 C                  3.00727119   -1.66932760   -5.64294306
 C                  3.47070808   -0.75490556   -4.55123104
 C                  3.50388993    0.57807245   -4.75109403
 C                  0.08097861    3.36788307   -5.83808299
 C                  2.35864570    2.62574931   -4.29675100
 C                 -0.70831595   -0.51455099   -8.14121004
 C                  0.84652406   -0.45343101    8.12164896
 C                 -0.65015895   -0.34478718    8.17737996
 C                 -1.42667384   -1.34599426    7.67402995
 C                 -0.78462070   -2.55950918    7.06412794
 C                  0.57570031   -2.65795102    7.01294294
 C                  1.43120218   -1.55512293    7.56914895
 C                  1.40010490    0.91346906    7.83630698
 C                  0.24315479    1.86638293    7.71331399
 C                 -1.02440012    1.08991278    7.92647698
 C                 -2.13765315    1.38802466    7.19757398
 C                 -2.65347488   -1.01476039    6.87152596
 C                 -1.61142366   -2.97220426    5.88121193
 C                 -0.99538060   -3.43539818    4.75750193
 C                  0.48931641   -3.54203901    4.70143392
 C                  1.24359937   -3.17731093    5.77265993
 C                  2.50341028   -2.39624579    5.56000994
 C                  2.62646116   -1.39841779    6.67148195
 C                  3.12721202   -0.16060873    6.41384596
 C                  2.48606189    1.05031919    7.02314898
 C                  0.27970668    2.86701594    6.78714200
 C                  1.47243166    3.00521209    5.88818300
 C                  2.51994176    2.14520121    6.00200499
 C                  3.17020582    1.60817330    4.76927798
 C                  3.54991398    0.19718834    5.01980997
 C                  3.43198208   -0.70552466    4.01355896
 C                  2.88382024   -2.05383873    4.29487594
 C                  2.05063028   -2.45182681    3.11776894
 C                  0.91755436   -3.15510294    3.31774593
 C                 -2.76434976   -2.02010239    5.76265095
 C                 -1.37494590   -0.87700218    1.45882896
 C                 -2.43998688   -1.02750331    2.29457096
 C                 -3.09856002    0.15553960    2.90365497
 C                 -2.59377816    1.37428566    2.63965398
 C                 -1.40875117    1.52489681    1.71225499
 C                  0.70517596    0.35022106    0.77242897
 C                  1.04779912   -1.06679490    1.21114495
 C                 -0.23037079   -1.80809205    1.57973795
 C                 -0.27887868   -2.80737307    2.52327093
 C                 -1.46304066   -2.98434222    3.40875293
 C                 -2.50151775   -2.12823133    3.29979894
 C                 -3.56191197   -0.20013647    4.28488697
 C                 -3.47279208    0.71245853    5.28849898
 C                 -2.91371323    2.06761760    5.00180699
 C                 -2.49640127    2.37344566    3.74039500
 C                 -1.24372435    3.12917681    3.52348700
 C                 -0.58422729    2.58086890    2.27594400
 C                  0.79779472    2.47353406    2.20481600
 C                  1.46836885    1.34787914    1.45617098
 C                  2.08668116   -1.35870779    2.07696395
 C                  2.93900103   -0.28144370    2.65893996
 C                  2.60959989    1.00239826    2.41130198
 C                  2.71526378    1.97432226    3.54222899
 C                  1.58680267    2.89603913    3.41665000
 C                  0.98567762    3.39724205    4.53035201
 C                 -0.50187340    3.52076988    4.58756601
 C                 -0.94267536    3.19161181    5.98376700
 C                 -2.09428528    2.49179568    6.17994300
 C                 -3.19194781   -1.62310543    4.53137495
 C                 -2.99321903    0.28632257    6.64698097
 C                 -0.80271006    0.53081789    0.78648397

