%nprocshared=24
%mem=41GB
#p opt freq=noraman b3lyp 6-31g(d) scrf=(pcm,solvent=n,n-dimethylformamide) nosymm empiricaldispersion=gd3 scf=(xqc,maxcyc=1024)

Opt freq

0 1
 C                 -0.16309145    0.93696196   -0.79496199
 C                  0.96579018    1.71818350   -1.44509899
 C                  0.78335972    2.69360041   -2.41319600
 C                 -0.59029245    3.04168675   -2.89983400
 C                 -1.61109510    2.31245327   -2.44921100
 C                 -1.39636158    1.20444038   -1.35017800
 C                  0.25319424   -0.52382584   -0.92986499
 C                  1.66162329   -0.63158217   -1.56460599
 C                  2.10523764    0.75222504   -1.87616299
 C                  2.94151255    0.95209843   -2.94490899
 C                  1.71834360    2.93902385   -3.62222100
 C                 -0.52452267    3.52253778   -4.35297400
 C                 -1.50313752    3.21593431   -5.22078100
 C                 -2.66045913    2.38057777   -4.74624600
 C                 -2.69568593    1.94982475   -3.45909000
 C                 -3.14191227    0.57234454   -3.14666900
 C                 -2.32573005    0.09338193   -1.94053300
 C                 -1.95443944   -1.19370789   -1.93917399
 C                 -0.58172028   -1.52362324   -1.46392099
 C                  2.09266779   -1.66582097   -2.35414498
 C                  1.15572731   -2.76810242   -2.75677798
 C                 -0.11125372   -2.69808502   -2.35473498
 C                 -1.21398954   -3.08120654   -3.32594799
 C                 -2.36134998   -2.14617209   -3.07366199
 C                 -3.10205119   -1.70966644   -4.10871299
 C                 -3.51658488   -0.26182164   -4.14888900
 C                 -3.47841909    0.20396138   -5.59804500
 C                 -3.07160569    1.45538257   -5.88032300
 C                  0.91065036    3.46093546   -4.79767200
 C                 -0.26950728    0.60586889   -8.28485099
 C                  0.60029425    1.58873031   -7.92101199
 C                  2.01377242    1.22785398   -7.47104599
 C                  2.40564004   -0.07304484   -7.43572699
 C                  1.42946557   -1.17897230   -7.84405499
 C                 -1.01939519   -1.69590546   -7.76648399
 C                 -2.19087964   -0.74732102   -7.51248199
 C                 -1.72789231    0.67334520   -7.83308700
 C                 -2.14803881    1.71284500   -7.06419000
 C                 -1.17349633    2.80943247   -6.65532300
 C                  0.11688470    2.75374908   -7.05676200
 C                  2.39503597    2.17156616   -6.32914199
 C                  3.11504619    1.71094751   -5.28363899
 C                  3.55193588    0.26149471   -5.24332599
 C                  3.22678628   -0.58434244   -6.25570698
 C                  2.76607895   -2.00148466   -5.93706898
 C                  1.65631113   -2.37409919   -6.91856098
 C                  0.60027848   -3.11702769   -6.49440498
 C                 -0.81554069   -2.75926136   -6.94323299
 C                 -3.02116054   -0.96674241   -6.45924399
 C                 -2.78927297   -2.15658930   -5.53594899
 C                 -1.75519157   -2.99888781   -5.76290899
 C                 -0.92054834   -3.49363441   -4.58871298
 C                  0.52768670   -3.57161972   -5.03754998
 C                  1.50889353   -3.23248525   -4.17108298
 C                  2.68504414   -2.40534970   -4.64381598
 C                  3.04315968   -1.44244952   -3.51829398
 C                  3.44595510   -0.20273933   -3.79806398
 C                  1.22499653    3.10473361   -6.07250100
 C                  2.74438799    2.12244033   -3.85835199
 C                  0.16937742   -0.85974890   -8.24321399
 C                 -0.56019132    0.63036480    8.24899601
 C                  0.15199532   -0.72198786    8.27743801
 C                  1.46716136   -0.80426524    7.94465101
 C                  2.23482776    0.45637412    7.54391201
 C                  1.60148119    1.65824582    7.51819301
 C                  0.12174515    1.75148312    7.89322200
 C                 -1.97933021    0.40394512    7.72918300
 C                 -2.14408051   -1.08761096    7.43558001
 C                 -0.82816018   -1.78560833    7.77510701
 C                 -0.38410969   -2.80859712    6.99739202
 C                  1.96376891   -1.95725001    7.07013102
 C                  3.19741594    0.08046158    6.41933901
 C                  3.40637453    0.94766167    5.39614201
 C                  2.69968790    2.28634434    5.36749101
 C                  1.85287373    2.62860694    6.36418900
 C                  0.53838241    3.31241831    6.02468000
 C                 -0.53167434    2.78001781    6.96904900
 C                 -1.78601424    2.57777321    6.50817700
 C                 -2.55370765    1.32357885    6.90866600
 C                 -2.86491431   -1.48942130    6.35602001
 C                 -3.49569481   -0.44877860    5.43627700
 C                 -3.35089243    0.86569647    5.69555600
 C                 -3.06438888    1.82832260    4.55076200
 C                 -2.11470039    2.88121205    5.04754800
 C                 -1.16713160    3.34639150    4.21319000
 C                  0.22883129    3.57051416    4.72519900
 C                  1.18195147    3.18208461    3.60745500
 C                  2.32985076    2.58244316    3.91527001
 C                  3.03075665   -1.40564650    6.12820902
 C                  1.90306217   -0.39050005    1.66927001
 C                  2.48472960   -1.29889677    2.51003802
 C                  1.75767320   -2.54723412    2.90878602
 C                  0.52289228   -2.72821270    2.44908602
 C                 -0.12034421   -1.68801301    1.50102101
 C                 -0.13432438    0.78523198    0.77442801
 C                  0.79804415    1.77593242    1.44245901
 C                  2.06348048    1.05953003    1.95451901
 C                  2.79202830    1.44733938    3.05112501
 C                  3.46251678    0.43524870    3.96362101
 C                  3.31793640   -0.86555137    3.70729902
 C                  2.12046336   -2.89976894    4.35161802
 C                  1.18062860   -3.40109138    5.18306502
 C                 -0.23049930   -3.61262406    4.66821602
 C                 -0.53264745   -3.29297320    3.38192202
 C                 -1.82387578   -2.59960882    3.04781901
 C                 -1.54906825   -1.61521169    1.90120201
 C                 -2.15677281   -0.41618098    1.84649701
 C                 -1.42327941    0.84153637    1.26392800
 C                  0.37809269    2.72925123    2.36790300
 C                 -1.06374236    2.82779654    2.77627700
 C                 -1.90231892    1.91115014    2.30682200
 C                 -2.95077667    1.37110665    3.27936400
 C                 -3.10969898   -0.07400843    2.99304900
 C                 -3.36953857   -0.94477255    4.00440300
 C                 -2.68483893   -2.28876222    4.03169401
 C                 -2.36505277   -2.63296607    5.48483001
 C                 -1.20159847   -3.25603551    5.78574501
 C                  3.09371686   -1.85057348    4.84779302
 C                  1.09256336   -2.90128242    6.62609502
 C                  0.48792325   -0.54787172    0.75141301

