Gaussian 09 15-May-2024 Gaussian 09 24-Apr-2013 EM64L-G09RevD.01 18 18 (5D, 7F) 6-311+G(d,p) UB3LYP 6-311+G(d,p) SP #p b3lyp 6-311+G(d,p) empiricaldispersion=gd3 scrf=(pcm,solvent=methylbutanoate) nosymm scf=maxcyc=512 112.08500000000001 0 2 AuxInfo=1/0/N:15,8,10,6,7,2,12,5,1/E:(2,3)(4,5)/CRV:2.3,3.3,4.3,5.3,7.3,8.3,9.1/rA:18nO1CHHC3C3C3C3HC3HC3HHCHHH/rB:s1;s2;s2;s2;s5;s5;s6;s6;s7;s7;s8s10;s8;s10;s12;s15;s15;s15;/rC:.0687,-2.9249,-.899;.1192,-2.552,.4298;-.7457,-2.9123,1.01;1.0528,-2.8608,.9272;.0696,-1.03,.2991;1.251,-.2973,.1273;-1.1623,-.3655,.2426;1.2007,1.0851,-.0336;2.2083,-.8116,.1323;-1.2053,1.017,.0814;-2.0843,-.9329,.3374;-.0263,1.7659,-.0555;2.1252,1.6458,-.1488;-2.1666,1.5246,.0564;-.0759,3.2675,-.1995;-.9944,3.5922,-.6993;-.0507,3.7546,.7845;.7788,3.6442,-.7709; g09 /mnt/data/applications/G09/g09/l1.exe "/scratch/Gau-5643.inp" -scrdir="/scratch/" nprocshared=8 mem=22GB #p b3lyp 6-311+G(d,p) empiricaldispersion=gd3 scrf=(pcm,solvent=methyl 1/38=1/1 2/12=2,15=1,17=6,18=5,40=1/2 3/5=4,6=6,7=111,11=2,16=1,25=1,30=1,70=2201,72=132,74=-5,124=31/1,2,3 4//1 5/5=2,7=512,38=5,53=132/2 6/7=2,8=2,9=2,10=2,28=1/1 99/5=1,9=1/99 Single point 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 16 12 1 1 12 12 12 12 1 12 1 12 1 1 12 1 1 1 15.9949146 12.0000000 1.0078250 1.0078250 12.0000000 12.0000000 12.0000000 12.0000000 1.0078250 12.0000000 1.0078250 12.0000000 1.0078250 1.0078250 12.0000000 1.0078250 1.0078250 1.0078250 0 0 1 1 0 0 0 0 1 0 1 0 1 1 0 1 1 1 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 (Enter /mnt/data/applications/G09/g09/l101.exe) 0.10000e-02 0.10000e-05 F 18 1.00e+00 60 F IExCor= 402 DFT=T Ex+Corr=B3LYP ExCW=0 ScaHFX= 0.200000 ScaDFX= 0.800000 0.720000 1.000000 0.810000 ScalE2= 1.000000 1.000000 IRadAn= 0 IRanWt= -1 IRanGd= 0 ICorTp=0 IEmpDi=131 NPDir=0 NMtPBC= 1 NCelOv= 1 NCel= 1 NClECP= 1 NCelD= 1 NCelK= 1 NCelE2= 1 NClLst= 1 CellRange= 0.0. One-electron integrals computed using PRISM. NBasis= 252 RedAO= T EigKep= 2.54D-06 NBF= 252 NBsUse= 252 1.00D-06 EigRej= -1.00D+00 NBFU= 252 Grimme-D3 -0.0118514117 PCM (using non-symmetric T matrix) UFF Total charges None On-the-fly selection MethylButanoate 5.560700 1.925989 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 112.08500000000001 AuxInfo=1/0/N:15,8,10,6,7,2,12,5,1/E:(2,3)(4,5)/CRV:2.3,3.3,4.3,5.3,7.3,8.3,9.1/rA:18nO1CHHC3C3C3C3HC3HC3HHCHHH/rB:s1;s2;s2;s2;s5;s5;s6;s6;s7;s7;s8s10;s8;s10;s12;s15;s15;s15;/rC:.0687,-2.9249,-.899;.1192,-2.552,.4298;-.7457,-2.9123,1.01;1.0528,-2.8608,.9272;.0696,-1.03,.2991;1.251,-.2973,.1273;-1.1623,-.3656,.2426;1.2007,1.0851,-.0336;2.2083,-.8116,.1323;-1.2053,1.017,.0814;-2.0843,-.9329,.3374;-.0263,1.766,-.0555;2.1252,1.6457,-.1488;-2.1666,1.5245,.0564;-.0759,3.2675,-.1995;-.9944,3.5922,-.6993;-.0507,3.7546,.7845;.7788,3.6442,-.7709; 0.000000 1.381079 0.000000 2.075564 1.102041 0.000000 2.075520 1.102027 1.801171 0.000000 2.241892 1.528423 2.170969 2.170990 0.000000 3.058667 2.540905 3.406465 2.692716 1.400726 0.000000 3.060871 2.541220 2.692268 3.406115 1.400751 2.416930 0.000000 4.255685 3.822751 4.566969 4.063936 2.421580 1.392669 2.786495 0.000000 3.179186 2.735272 3.729491 2.483146 2.156291 1.086778 3.401731 2.154185 0.000000 4.257158 3.822808 4.063631 4.566433 2.421389 2.786195 1.392615 2.409779 3.872917 0.000000 3.183123 2.735968 2.482416 3.729133 2.156401 3.401764 1.086735 3.873174 4.299192 2.154123 0.000000 4.767042 4.347596 4.851690 4.851508 2.819985 2.433450 2.433657 1.403394 3.416512 1.403510 3.416660 0.000000 5.067809 4.688293 5.510048 4.755718 3.403798 2.148472 3.873746 1.087281 2.474820 3.397164 4.960397 2.156836 0.000000 5.070233 4.688583 4.755414 5.509500 3.403709 3.873494 2.148467 3.397100 4.960188 1.087327 2.474812 2.156835 4.298433 0.000000 6.233519 5.856744 6.332605 6.332478 4.328823 3.817780 3.817724 2.533824 4.686956 2.533637 4.686727 1.509298 2.734542 2.733966 0.000000 6.606307 6.345629 6.729981 6.962668 4.847068 4.566562 4.071799 3.398154 5.508469 2.699217 4.768572 2.164984 3.718053 2.494099 1.094958 0.000000 6.889393 6.318829 6.706764 6.708293 4.810631 4.306231 4.301689 3.059606 5.136016 3.053117 5.129091 2.158880 3.170604 3.159145 1.098195 1.765996 0.000000 6.608653 6.345898 6.963028 6.728630 4.847310 4.070070 4.568720 2.696422 4.765962 3.400779 5.511385 2.165134 2.488756 3.721927 1.094930 1.775374 1.766187 0.000000 4.4748556 0.9951579 0.8737857 Precomputing XC quadrature grid using IXCGrd= 4 IRadAn= 0 IRanWt= -1 IRanGd= 0 AccXCQ= 0.00D+00. Generated NRdTot= 0 NPtTot= 0 NUsed= 0 NTot= 32 NSgBfM= 261 261 261 261 261 MxSgAt= 18 MxSgA2= 18. 1 open 1 1 1 -385.324532452294 -385.401019430141 -0.076486977846 -385.525560411224 -0.124540981083 -385.537843051527 -0.012282640303 -385.546069873112 -0.008226821585 -385.546382535784 -0.000312662672 -385.546500368587 -0.000117832803 -385.546524032976 -0.000023664389 -385.546528945592 -0.000004912616 -385.546529958366 -0.000001012773 -385.546530100251 -0.000000141885 -385.546530149410 -0.000000049160 -385.546530168033 -0.000000018623 -385.546530173335 -0.000000005301 -385.546530174558 -0.000000001224 -385.546530174830 -0.000000000272 -385.546530174912 -0.000000000083 -385.546530174980 -0.000000000068 -385.546530175083 -0.000000000102 -385.546530175256 -0.000000000173 -385.546530175281 -0.000000000025 -385.546530175292 -0.000000000011 -385.546530175286 0.000000000006 -385.546530175 23 0.7554 3.837822458144e+02 -1.710617013042e+03 5.345460069124e+02 Using DIIS extrapolation, IDIIS= 1040. Two-electron integral symmetry not used. Keep R1 and R2 ints in memory in canonical form, NReq=1025705278. IVT= 474283 IEndB= 474283 NGot= 2952790016 MDV= 1936076972 LenX= 1936076972 LenY= 1936008410 Requested convergence on RMS density matrix=1.00D-08 within 512 cycles. Requested convergence on MAX density matrix=1.00D-06. Requested convergence on energy=1.00D-06. No special actions if energy rises. FoFCou: FMM=F IPFlag= 0 FMFlag= 0 FMFlg1= 0 NFxFlg= 0 DoJE=F BraDBF=F KetDBF=F FulRan=T wScrn= 0.000000 ICntrl= 600 IOpCl= 0 I1Cent= 0 NGrid= 0 NMat0= 1 NMatS0= 31878 NMatT0= 0 NMatD0= 1 NMtDS0= 0 NMtDT0= 0 Symmetry not used in FoFCou. 0.7554 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 O C H H C C C C H C H C H H C H H H 17 13 1 1 13 13 13 13 1 13 1 13 1 1 13 1 1 1 0.05853 -0.02427 0.00559 0.00556 0.06893 0.00052 0.00053 -0.00125 -0.00031 -0.00123 -0.00030 0.00376 0.00051 0.00051 -0.00162 0.00052 0.00227 0.00049 -35.48079 -27.27914 24.99493 24.84777 77.49575 0.58999 0.59870 -1.40925 -1.37167 -1.38682 -1.35876 4.22625 2.28487 2.28767 -1.81568 2.31767 10.13987 2.19643 -12.66043 -9.73388 8.91881 8.86630 27.65241 0.21052 0.21363 -0.50286 -0.48944 -0.49485 -0.48484 1.50803 0.81530 0.81630 -0.64788 0.82700 3.61816 0.78374 -11.83512 -9.09934 8.33741 8.28833 25.84980 0.19680 0.19970 -0.47008 -0.45754 -0.46259 -0.45323 1.40972 0.76215 0.76308 -0.60565 0.77309 3.38230 0.73265 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 -1.641587 -0.048688 -0.003487 -0.001031 -0.079680 -0.024907 -0.021651 0.005806 0.005890 0.006033 0.005827 -0.036459 0.000311 0.000312 -0.002506 -0.000452 -0.001227 -0.000584 3.166596 0.033568 -0.010249 -0.010264 0.149617 -0.022952 -0.023691 0.016064 -0.001988 0.015867 -0.002263 -0.029192 0.001784 0.001683 0.001282 0.001461 0.001660 0.001555 -1.525009 0.015120 0.013736 0.011295 -0.069937 0.047859 0.045342 -0.021870 -0.003903 -0.021900 -0.003564 0.065652 -0.002094 -0.001996 0.001224 -0.001008 -0.000433 -0.000971 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 -0.173061 -0.002235 0.000349 0.000065 -0.001623 0.007222 -0.007622 0.000436 0.002723 -0.001930 -0.002016 0.000344 0.000747 -0.000828 -0.000067 -0.000917 -0.000053 0.000767 0.028088 0.002881 -0.012539 0.013926 -0.002548 -0.008329 0.015265 -0.001804 0.001230 -0.000307 -0.002283 0.004553 0.000397 -0.000626 0.000155 0.000185 0.000007 -0.000198 -0.790381 0.002163 -0.000842 -0.000069 0.104129 -0.004456 -0.003182 -0.009679 0.002564 -0.009582 0.002675 0.011638 -0.000002 0.000043 0.000836 -0.000367 0.000780 -0.000446 0.0411 0.1631 0.9858 0.9985 0.0283 -0.0464 -0.0354 0.9862 -0.1617 -1.6546 -1.6478 3.3024 119.725 119.233 -238.958 42.721 42.545 -85.266 39.936 39.772 -79.708 1 O 17 0.9985 0.0283 -0.0459 0.0488 -0.1099 0.9927 -0.023 0.9935 0.1111 -0.0489 0.015 0.0339 -6.56 2.016 4.544 -2.341 0.719 1.621 -2.188 0.672 1.516 2 C 13 0.2996 0.9352 0.189 0.8328 -0.353 0.4264 -0.4655 -0.0296 0.8846 -0.0103 -0.0101 0.0204 -5.499 -5.365 10.864 -1.962 -1.914 3.877 -1.834 -1.79 3.624 3 H 1 -0.3381 0.9148 0.2209 0.7668 0.4039 -0.4988 0.5456 -7.0E-4 0.8381 -0.0103 -0.0101 0.0204 -5.498 -5.365 10.864 -1.962 -1.915 3.876 -1.834 -1.79 3.624 4 H 1 0.0553 -0.3695 0.9276 0.9984 0.0289 -0.048 -0.0091 0.9288 0.3705 -0.1116 -0.0796 0.1912 -14.971 -10.682 25.653 -5.342 -3.812 9.154 -4.994 -3.563 8.557 5 C 13 0.7698 -0.6367 0.0451 0.6272 0.7677 0.1316 -0.1184 -0.073 0.9903 -0.0314 -0.0178 0.0492 -4.209 -2.391 6.6 -1.502 -0.853 2.355 -1.404 -0.797 2.202 6 C 13 0.7238 0.6802 -0.116 -0.6548 0.7301 0.1954 0.2176 -0.0655 0.9738 -0.0313 -0.0177 0.049 -4.195 -2.376 6.571 -1.497 -0.848 2.345 -1.399 -0.793 2.192 7 C 13 0.0548 0.2323 0.9711 0.9962 -0.0781 -0.0376 0.0671 0.9695 -0.2358 -0.0243 0.0058 0.0184 -3.259 0.784 2.476 -1.163 0.28 0.883 -1.087 0.261 0.826 8 C 13 0.0539 -0.5928 0.8036 -0.3712 0.7352 0.5672 0.927 0.3289 0.1804 -0.0057 -0.0014 0.0071 -3.048 -0.738 3.786 -1.087 -0.264 1.351 -1.017 -0.246 1.263 9 H 1 0.0248 0.2336 0.972 0.9892 0.1347 -0.0576 -0.1444 0.963 -0.2277 -0.0242 0.0058 0.0184 -3.249 0.777 2.472 -1.159 0.277 0.882 -1.084 0.259 0.825 10 C 13 0.0554 -0.5931 0.8032 0.3797 0.7565 0.5325 0.9234 -0.2755 -0.2671 -0.0057 -0.0014 0.0071 -3.039 -0.743 3.782 -1.085 -0.265 1.35 -1.014 -0.248 1.262 11 H 1 0.9985 0.0283 -0.0477 -0.0338 0.9924 -0.1184 0.0439 0.1198 0.9918 -0.0367 -0.0306 0.0673 -4.92 -4.105 9.026 -1.756 -1.465 3.221 -1.641 -1.369 3.011 12 C 13 -0.168 0.0324 0.9853 0.9047 -0.3918 0.1671 0.3915 0.9195 0.0365 -0.0022 1.0E-4 0.0021 -1.154 0.032 1.121 -0.412 0.012 0.4 -0.385 0.011 0.374 13 H 1 0.2591 0.045 0.9648 0.8589 0.4462 -0.2515 -0.4418 0.8938 0.0769 -0.0022 1.0E-4 0.0021 -1.153 0.035 1.119 -0.412 0.012 0.399 -0.385 0.012 0.373 14 H 1 0.9985 0.0282 -0.0476 0.0538 -0.6951 0.7169 0.0129 0.7183 0.6956 -0.0025 4.0E-4 0.0021 -0.338 0.057 0.281 -0.12 0.02 0.1 -0.113 0.019 0.094 15 C 13 -0.1783 0.0776 0.9809 0.9114 0.3889 0.1348 -0.371 0.918 -0.1401 -0.0011 -8.0E-4 0.0019 -0.571 -0.436 1.007 -0.204 -0.155 0.359 -0.191 -0.145 0.336 16 H 1 0.9989 0.0283 -0.0369 0.044 -0.3137 0.9485 -0.0152 0.9491 0.3146 -0.0012 -7.0E-4 0.0019 -0.656 -0.368 1.024 -0.234 -0.131 0.365 -0.219 -0.123 0.342 17 H 1 PT847.100S 2024-05-15T10:15:00.000 -10.19165 -10.18532 -10.18531 -10.17414 -1.02869 -0.87577 -0.79453 -0.76232 -0.71518 -0.65206 -0.62563 -0.58936 -0.51775 -0.49655 -0.47580 -0.45435 -0.44182 -0.43490 -0.43040 -0.42789 -0.39238 -0.37664 -0.36839 -0.35454 -0.32359 -0.29208 -0.26971 -0.25684 -0.02936 -0.02827 0.00544 0.01666 0.02220 0.03436 0.03589 0.04639 0.05239 0.05402 0.06286 0.07303 0.08287 0.08695 0.09322 0.09865 0.10596 0.11916 0.12360 0.13665 0.13690 0.14442 0.14782 0.15041 0.16080 0.16156 0.17112 0.18207 0.18879 0.18893 0.19669 0.19877 0.20737 0.21220 0.21502 0.21871 0.22567 0.22842 0.24225 0.24760 0.25426 0.25468 0.25881 0.26594 0.27735 0.28061 0.28592 0.29508 0.30331 0.32119 0.32753 0.33931 0.35565 0.36319 0.40747 0.42567 0.45158 0.45207 0.47208 0.49800 0.51840 0.53269 0.53996 0.54318 0.55696 0.56191 0.56763 0.59510 0.60213 0.61563 0.61837 0.63003 0.63079 0.63425 0.63797 0.66765 0.68052 0.68365 0.68942 0.70203 0.70918 0.71382 0.73723 0.75097 0.77358 0.82807 0.84775 0.85199 0.86659 0.88423 0.88860 0.93084 0.93638 0.94196 0.96890 0.99516 1.00771 1.00842 1.05142 1.06463 1.07847 1.09696 1.10211 1.14192 1.14636 1.23238 1.31135 1.31560 1.35693 1.40713 1.41819 1.44174 1.44964 1.47540 1.49645 1.49731 1.51644 1.54046 1.56012 1.56549 1.58602 1.59961 1.60066 1.60965 1.63355 1.65971 1.66265 1.66959 1.68548 1.71178 1.72032 1.76606 1.76815 1.80124 1.82595 1.86170 1.89055 1.91017 1.92213 1.92294 1.93415 1.97568 1.99637 2.01807 2.05281 2.06538 2.10549 2.10605 2.17025 2.19602 2.23768 2.26734 2.30319 2.34037 2.35326 2.38635 2.39955 2.43062 2.44710 2.45160 2.53824 2.54490 2.57966 2.58736 2.62670 2.63285 2.65412 2.67866 2.68268 2.70981 2.71243 2.73928 2.76772 2.76853 2.78474 2.78575 2.84422 2.84898 2.88124 2.89778 2.90281 2.92063 2.92091 2.96710 3.02267 3.07757 3.11695 3.16337 3.17680 3.21682 3.25059 3.33230 3.41106 3.48166 3.57620 3.61883 3.68348 3.79371 3.79506 3.81740 3.97779 4.01782 4.13505 4.14352 4.25657 4.35474 4.82720 5.01195 5.04315 5.55591 23.56742 23.81505 23.90825 23.93184 23.96817 24.04212 24.08447 24.16408 49.85411 -19.14163 -10.23188 -10.20498 -10.20021 -10.19106 -10.19105 -10.18555 -10.18553 -10.17417 -0.98273 -0.87271 -0.78926 -0.76147 -0.70918 -0.64434 -0.62457 -0.58679 -0.50868 -0.49470 -0.46777 -0.43867 -0.43508 -0.43405 -0.42726 -0.41374 -0.39160 -0.36732 -0.36098 -0.35368 -0.27709 -0.26476 -0.26174 -0.14927 -0.02606 -0.02255 0.00586 0.01695 0.02226 0.03491 0.03738 0.04640 0.05293 0.05503 0.06426 0.07305 0.08299 0.08729 0.09388 0.10081 0.10605 0.12140 0.12420 0.13687 0.13714 0.14484 0.14874 0.15160 0.16095 0.16280 0.17186 0.18395 0.18911 0.18948 0.19707 0.20046 0.20894 0.21372 0.21588 0.21906 0.22588 0.22920 0.24349 0.24800 0.25480 0.25713 0.25942 0.26720 0.28191 0.28235 0.28862 0.29593 0.30409 0.32830 0.32834 0.34312 0.35636 0.36730 0.40929 0.42694 0.45196 0.45263 0.47242 0.49933 0.51914 0.53525 0.54099 0.54445 0.55726 0.56326 0.56866 0.59531 0.60475 0.61619 0.62080 0.63096 0.63130 0.63581 0.64024 0.66886 0.68168 0.68425 0.69085 0.70218 0.71077 0.71498 0.73754 0.75215 0.77421 0.82877 0.84849 0.85585 0.86701 0.88873 0.89033 0.93242 0.93740 0.94424 0.97048 0.99651 1.00886 1.01690 1.05549 1.06664 1.08309 1.10165 1.10465 1.14665 1.15977 1.26084 1.31608 1.31650 1.35795 1.40780 1.42133 1.44546 1.45076 1.47588 1.49774 1.50337 1.51759 1.54148 1.56155 1.56678 1.58837 1.60129 1.61013 1.61097 1.63826 1.66080 1.66348 1.67248 1.68914 1.71496 1.72167 1.76647 1.76921 1.80126 1.82682 1.86342 1.89131 1.91179 1.92362 1.92442 1.93584 1.97741 1.99715 2.02004 2.05536 2.06620 2.10685 2.10798 2.17116 2.20086 2.23896 2.27287 2.30484 2.34187 2.35415 2.38651 2.40140 2.43101 2.44869 2.45401 2.53906 2.54539 2.58046 2.58816 2.62981 2.63378 2.65750 2.67955 2.69826 2.71034 2.71336 2.74356 2.76880 2.77246 2.78678 2.79711 2.86050 2.87569 2.88472 2.89927 2.91231 2.92219 2.93985 2.98241 3.04731 3.08907 3.13287 3.16565 3.19385 3.23595 3.26056 3.33419 3.41193 3.48227 3.57781 3.62060 3.68561 3.79412 3.79626 3.81758 3.97828 4.03460 4.13638 4.14441 4.26169 4.35874 4.82868 5.03074 5.13311 5.57487 23.56828 23.81499 23.90896 23.93211 23.96888 24.04304 24.08469 24.16454 49.87648 0.0158 3.0888 2.2963 3.8489 -48.2926 -53.6788 -58.9923 -0.1345 -0.2218 -7.9236 5.3620 -0.0242 -5.3378 -0.1345 -0.2218 -7.9236 -3.6582 22.4351 -0.0758 -1.2716 -1.7483 0.2148 -1.6531 1.7248 19.7282 -0.6140 -299.1011 -1374.1038 -126.4081 13.5297 3.0763 14.3715 -54.1007 5.6975 2.3324 -268.1806 -82.0274 -263.6649 -5.9842 1.9693 5.8651 GINC-KIMIK2129 EGARCIAP 2024-05-15T00:00:00.000 0 Single point 0 2 Version=EM64L-G09RevD.01 HF=-385.5465302 S2=0.755401 S2-1=0. S2A=0.750022 RMSD=1.991e-09 Dipole=0.0062293,1.2152255,0.9034359 Quadrupole=3.9865017,-0.0179969,-3.9685047,-0.1000333,-0.1648743,-5.8910363 PG=C01 [X(C8H9O1)] 0 0.068734 -2.924904 -0.899013 0 0.119199 -2.55202 0.429817 0 -0.745691 -2.912285 1.010049 0 1.052839 -2.860805 0.927243 0 0.069581 -1.030007 0.299087 0 1.25096 -0.297286 0.127343 0 -1.162254 -0.365554 0.242621 0 1.200741 1.085141 -0.033594 0 2.208296 -0.81165 0.132325 0 -1.205327 1.017032 0.081446 0 -2.084292 -0.932885 0.337357 0 -0.026259 1.765954 -0.055498 0 2.125202 1.645745 -0.148813 0 -2.166618 1.524549 0.056407 0 -0.075913 3.267549 -0.199467 0 -0.994416 3.592237 -0.699329 0 -0.050698 3.754558 0.784514 0 0.778753 3.644247 -0.770883