%nprocshared=8
%mem=22GB
#p opt freq=noraman b3lyp 6-31g(d) scrf=(solvent=ethanol,pcm) nosymm empiricaldispersion=gd3 scf=maxcyc=512

Opt freq

-1 1
 O                  1.39550530   -1.20687584   -0.51291761
 C                  1.84936863   -0.10362516    0.15894121
 H                  1.96824227   -0.26631980    1.26354224
 H                  2.87236026    0.20129424   -0.17287471
 C                  0.97129715    1.15261058    0.03264048
 C                  1.52299919    2.43625965   -0.05902985
 C                 -0.42659984    1.04129182    0.00706867
 C                  0.71319181    3.57093812   -0.16820978
 H                  2.60665115    2.55142501   -0.06073634
 C                 -1.23516866    2.17337207   -0.09747873
 H                 -0.86660370    0.04914167    0.07038005
 C                 -0.68266829    3.46017896   -0.18851386
 H                  1.17095271    4.55562230   -0.25144817
 H                 -2.31870374    2.05925323   -0.11505277
 C                 -1.57042227    4.67993404   -0.29705254
 H                 -2.36020227    4.53637794   -1.04462582
 H                 -2.07067948    4.89905869    0.65604344
 H                 -0.99780258    5.57001745   -0.57941883
 O                 -0.60059581   -2.23355177    0.57087864
 H                  0.26228449   -1.78973963    0.10237492
 C                 -0.27799763   -2.33355215    1.93195177
 H                 -0.28182720   -1.35521145    2.45371307
 H                 -1.01173468   -2.97330984    2.44927280
 H                  0.71853926   -2.78321188    2.10457956
 O                 -1.18413317   -4.59533878   -0.34615397
 H                 -0.97875144   -3.61021387    0.03904030
 C                 -0.18348384   -4.84186346   -1.29721454
 H                  0.80964700   -5.03673830   -0.84431832
 H                 -0.44055905   -5.73109915   -1.89592417
 H                 -0.05112117   -4.00348213   -2.00762066

