%nprocshared=8
%mem=22GB
#p opt freq=noraman b3lyp 6-31g(d) scrf=(solvent=ethanol,pcm) nosymm empiricaldispersion=gd3 scf=maxcyc=512

Opt freq

-1 1
 O                  1.19603248   -1.99161011   -0.48509933
 C                  1.65517737   -1.11855557    0.54393855
 H                  1.44818998   -1.55808772    1.52181465
 H                  2.73339359   -0.96709238    0.46026534
 C                  0.91911830    0.17576209    0.36080974
 C                  1.52725440    1.26891163   -0.25203033
 C                 -0.41340624    0.29235871    0.75973561
 C                  0.82398068    2.45332201   -0.45372903
 H                  2.55863432    1.19198343   -0.57877693
 C                 -1.11486889    1.47266617    0.55489805
 H                 -0.90217601   -0.55391085    1.23010616
 C                 -0.50659296    2.57595702   -0.05229244
 H                  1.31629062    3.29327637   -0.93145440
 H                 -2.15000837    1.54372724    0.87140967
 C                 -1.26806551    3.86362554   -0.24415366
 H                 -2.27805240    3.67614239   -0.61646405
 H                 -1.37088987    4.40398939    0.70196807
 H                 -0.76345725    4.52699951   -0.94875661
 O                 -1.33063761   -3.07792807   -0.74099840
 H                 -0.52653356   -2.70206719   -1.10671041
 C                 -0.99707978   -4.15520718    0.13826771
 H                 -0.37955905   -3.78965046    0.93195305
 H                 -1.89351543   -4.57252683    0.54710442
 H                 -0.46857974   -4.90951992   -0.40634224

