%nprocshared=8
%mem=22GB
#p opt=calcfc freq=noraman b3lyp 6-31g(d) scrf=(solvent=ethanol,pcm) nosymm empiricaldispersion=gd3 scf=maxcyc=512

Opt freq

-1 1
 O                 -0.22344183   -3.15810098   -0.80629213
 C                  0.11543351   -2.57486838    0.34993866
 H                 -0.55080649   -2.82704659    1.24421356
 H                  1.15305548   -2.82721749    0.75302419
 C                  0.09023261   -1.03246685    0.27318470
 C                  1.25333965   -0.26853615    0.12867770
 C                 -1.13449673   -0.34668245    0.23151260
 C                  1.20345979    1.12164035   -0.03211602
 H                  2.22032718   -0.77121765    0.14684400
 C                 -1.19255763    1.03755359    0.07893709
 H                 -2.05782434   -0.91756047    0.32478210
 C                 -0.01985268    1.80098793   -0.05397515
 H                  2.12868742    1.68659449   -0.13914881
 H                 -2.15861742    1.54124758    0.06493406
 C                 -0.08646596    3.30580717   -0.18955660
 H                 -0.86311450    3.61269520   -0.90060379
 H                 -0.32609281    3.78564384    0.76939415
 H                  0.86736480    3.72105771   -0.53272038

