%nprocshared=24
%mem=41GB
#p b3lyp opt freq=noraman 6-31G(d) scrf=(solvent=methylpropanoate,pcm) nosymm empiricaldispersion=gd3 scf=maxcyc=512

Opt freq

0 1
 C                  0.01837700    0.00145300   -0.66492700
 H                 -0.99204200    0.00675600   -1.08414500
 H                  0.54860700    0.89152400   -1.03554000
 H                  0.54031200   -0.89291800   -1.03700300
 O                 -0.12059600    0.00095700    0.75319500
 H                  0.77211400    0.00081100    1.13153900


