%nprocshared=8
%mem=22GB
#p opt freq=noraman b3lyp 6-31g(d) scrf=(solvent=ethanol,pcm) nosymm empiricaldispersion=gd3 scf=maxcyc=512

Opt freq

0 1
 C                  0.01930218   -0.00112733   -0.66653162
 H                 -0.99994776    0.00880478   -1.08053403
 H                  0.55273548    0.89398695   -1.04165841
 H                  0.54477343   -0.89563300   -1.04436813
 O                 -0.12332605   -0.00042090    0.75279131
 H                  0.77323415    0.00297242    1.14341983

