%nprocshared=24
%mem=41GB
#p b3lyp opt freq=noraman 6-31G(d) scrf=(solvent=ethanol,pcm) nosymm empiricaldispersion=gd3 scf=maxcyc=512

Opt freq

0 1
 C                  0.08556200   -0.71550662    0.08277511
 C                 -1.23035434   -0.96735310    0.82876528
 C                 -2.51349343   -0.62237967    0.42791985
 C                 -0.99517787   -1.62685734    2.04923319
 C                 -3.58657495   -0.94790688    1.25949004
 H                 -2.68102038   -0.11296974   -0.51569142
 C                 -2.05144531   -1.96692975    2.88612215
 C                 -3.33593507   -1.61397120    2.46320056
 H                 -4.60416254   -0.69782865    0.98845739
 H                 -1.90626303   -2.47657558    3.83033890
 C                  1.10410492   -1.27974129    1.07861211
 C                  2.48739105   -1.28740563    0.96669111
 C                  0.45629977   -1.81777709    2.20605476
 C                  3.24106684   -1.84956643    1.99870333
 H                  2.97478854   -0.86533962    0.09368853
 C                  1.18943007   -2.39030446    3.23886806
 C                  2.58060840   -2.39034722    3.10616274
 H                  4.32226618   -1.87574843    1.95546587
 H                  0.72294095   -2.81668894    4.11801628
 C                  0.11535369   -1.47676186   -1.24488299
 C                  0.26898371   -0.81026602   -2.46178809
 C                 -0.02319699   -2.87219467   -1.24957641
 C                  0.28501348   -1.53008210   -3.66011259
 H                  0.38005420    0.26720791   -2.47258824
 C                 -0.00682525   -3.58079000   -2.44668564
 H                 -0.14116149   -3.40795836   -0.31110275
 C                  0.14571501   -2.92169473   -3.67716239
 H                  0.40981913   -0.99363072   -4.59789410
 H                 -0.11190662   -4.66305814   -2.42788967
 O                  0.29766653    0.65846765   -0.21359517
 C                  0.35234305    1.55049110    0.91346741
 H                 -0.48680505    1.33926953    1.59031807
 H                  1.28342344    1.39732553    1.47295721
 C                  0.26310244    2.95603788    0.38368603
 C                  1.30699637    3.86791813    0.55686159
 C                 -0.88321589    3.37003381   -0.30970089
 C                  1.20555247    5.16923011    0.05793106
 H                  2.20834322    3.56072477    1.08220666
 C                 -0.97912907    4.66504224   -0.81154568
 H                 -1.69813311    2.66631093   -0.46064843
 C                  0.06271768    5.58989735   -0.63238340
 H                  2.02975507    5.86384892    0.20243452
 H                 -1.87442084    4.96802535   -1.34993863
 C                 -0.06304301    7.00325014   -1.15107455
 H                 -0.56918323    7.02902695   -2.12242273
 H                 -0.65313868    7.62329079   -0.46329815
 H                  0.91658135    7.47905658   -1.26263278
 C                  0.13681708   -3.69667162   -4.97354831
 H                 -0.88577414   -3.98003423   -5.25532499
 H                  0.55415907   -3.10763660   -5.79634868
 H                  0.71493864   -4.62365201   -4.88829872
 H                 -4.16510935   -1.86347598    3.09178419
 H                  3.16667539   -2.82158997    3.89067226

