%nprocshared=24
%mem=41GB
#p b3lyp opt freq=noraman 6-31G(d) scrf=(solvent=ethanol,pcm) nosymm empiricaldispersion=gd3 scf=maxcyc=512

Opt freq

0 1
 C                  0.59781406   -0.06820222   -0.20184839
 C                 -0.18073559   -0.87976543   -1.24176393
 C                 -0.61845423   -0.61358486   -2.55215950
 C                 -0.66685749   -2.03629645   -0.62860779
 C                 -1.47378749   -1.47620370   -3.22081129
 H                 -0.31137583    0.30401162   -3.04340783
 C                 -1.51492459   -2.92157659   -1.29776016
 C                 -1.93821629   -2.66416387   -2.61360581
 H                 -1.81176137   -1.21122874   -4.21748318
 H                 -1.83245203   -3.81904297   -0.78023627
 C                  0.56151164   -0.86214663    1.11583934
 C                  1.16492992   -0.71203629    2.37157600
 C                 -0.14194377   -2.04738521    0.87717767
 C                  1.03666356   -1.68401381    3.35768125
 H                  1.76176779    0.16969779    2.57502234
 C                 -0.28535141   -3.02494480    1.86147304
 C                  0.29776694   -2.86206978    3.13226572
 H                  1.54187986   -1.53802424    4.30746804
 H                 -0.86801013   -3.90890147    1.62983056
 C                  2.04909764    0.21151856   -0.62802022
 C                  2.69387061    1.38255754   -0.20819267
 C                  2.79216998   -0.73092902   -1.34750370
 C                  4.03238401    1.61171058   -0.52336961
 H                  2.14362938    2.11807784    0.36795155
 C                  4.13385951   -0.49973847   -1.65450021
 H                  2.32158461   -1.65114916   -1.67911381
 C                  4.77822942    0.67768299   -1.25582655
 H                  4.50696325    2.53196261   -0.18946649
 H                  4.68644236   -1.24821356   -2.21799144
 O                 -0.01562357    1.25100255   -0.09899692
 C                 -1.44798278    1.28589848    0.09358593
 H                 -1.94043053    1.09287289   -0.86641579
 H                 -1.74932710    0.49947826    0.79301952
 C                 -1.79650246    2.64755800    0.63133918
 C                 -2.08643041    2.83352387    1.98713974
 C                 -1.79954762    3.76505313   -0.21520137
 C                 -2.37249543    4.10558924    2.48705870
 H                 -2.08767428    1.97799318    2.65859926
 C                 -2.08024599    5.03381528    0.28857596
 H                 -1.55921137    3.63602577   -1.26713266
 C                 -2.37507814    5.22657856    1.64728700
 H                 -2.59547892    4.22804751    3.54448833
 H                 -2.07285454    5.89002840   -0.38242642
 C                 -2.71175891    6.60028394    2.17817969
 H                 -2.12070742    7.37694492    1.68062020
 H                 -3.76962856    6.83970971    2.00685468
 H                 -2.53112128    6.66999264    3.25579661
 C                  6.21912946    0.94676442   -1.62032129
 H                  6.28807835    1.57450445   -2.51870746
 H                  6.74299992    1.47594434   -0.81665269
 H                  6.76086869    0.01817651   -1.82809247
 C                  1.22925487    3.88670011   -2.20083738
 H                  1.28127053    4.47078788   -3.12524171
 H                  0.81487222    4.53062206   -1.41008974
 H                  2.25021036    3.59763950   -1.91330964
 O                  0.40455569    2.75628187   -2.45423133
 H                  0.34035623    2.24642318   -1.61972552
 N                  0.20146435   -3.87816682    4.19017527
 O                  0.73574703   -3.64086663    5.27785930
 O                 -0.40966775   -4.92227558    3.94282676
 N                 -2.86886114   -3.54300721   -3.33640216
 O                 -3.20362814   -4.60458676   -2.80179406
 O                 -3.27354909   -3.17920899   -4.44487198

