%nprocshared=24
%mem=41GB
#p b3lyp opt=calcfc freq=noraman 6-31G(d) scrf=(solvent=ethanol,pcm) nosymm empiricaldispersion=gd3 scf=maxcyc=512

Opt freq calcfc

0 1
 C                 -0.00530000    0.15098800   -0.28833600
 C                  1.10319800    1.06497200    0.25692200
 C                  1.27662300    1.52806700    1.55647100
 C                  2.35988000    2.36112600    1.83798600
 C                  3.24165600    2.70277800    0.80863300
 C                  3.09263700    2.24329500   -0.50042900
 C                  2.00599000    1.41574600   -0.76263000
 H                  3.80238600    2.52978100   -1.26628500
 H                  2.52818500    2.74199900    2.83691700
 H                  0.59524900    1.24301300    2.35151700
 C                 -0.03021700   -1.17463800    0.48811300
 C                  0.69590000   -2.28337400    0.03600900
 C                  0.72469700   -3.46760800    0.77198600
 C                  0.03716800   -3.58908500    1.98556500
 C                 -0.68156300   -2.47558000    2.43878100
 C                 -0.71057500   -1.28716100    1.71058300
 H                 -1.28687000   -0.45865100    2.10762900
 H                 -1.23010900   -2.53506100    3.37552100
 H                  1.29057600   -4.31357700    0.38963900
 H                  1.24185200   -2.23216300   -0.89965800
 C                 -1.38174300    0.92167300   -0.14323900
 H                 -1.43192900    1.35963100    0.85681200
 C                 -1.47324000    2.03175300   -1.09603700
 N                 -1.54138000    2.91006800   -1.85084200
 C                 -2.61782800    0.01220800   -0.30545700
 O                 -2.80901000   -0.74298200   -1.23193900
 O                 -3.44407000    0.18469100    0.72689200
 C                 -4.63832100   -0.63641000    0.72159400
 H                 -5.22664000   -0.43511900   -0.17598900
 H                 -5.18556300   -0.35159400    1.61843200
 H                 -4.35841600   -1.69172600    0.75406600
 C                  0.41845700    0.01174600   -1.75697700
 C                  1.58237900    0.76718600   -2.00576700
 C                  2.15739400    0.80911600   -3.27125400
 C                  1.53613700    0.06968600   -4.27710100
 C                  0.38806000   -0.69384400   -4.05379400
 C                 -0.17646300   -0.72458300   -2.77775900
 H                 -1.06855700   -1.30605700   -2.58931300
 H                 -0.05006600   -1.25351100   -4.87006800
 H                  3.04971500    1.38452900   -3.48279900
 C                  0.08546100   -4.86503500    2.79101900
 H                  0.30402000   -5.73069900    2.15763700
 H                  0.86868500   -4.81336000    3.55860200
 H                 -0.86309600   -5.04751600    3.30709300
 N                  4.37726500    3.58142300    1.11795800
 O                  5.15490000    3.86655200    0.20486800
 O                  4.49763900    3.99168800    2.27407400
 N                  2.11832600    0.09195000   -5.62599400
 O                  1.55618700   -0.55299800   -6.51320500
 O                  3.14184300    0.75560300   -5.80431900

