%nprocshared=24
%mem=41GB
#p opt freq=noraman b3lyp 6-31g(d) scrf=(solvent=ethanol,pcm) nosymm empiricaldispersion=gd3 scf=maxcyc=512

Opt freq

0 1
 C                 -0.57388610   -0.63071681    0.02054292
 C                 -1.78399123    0.31759615   -0.04157002
 C                 -2.23861751    0.98443439    1.10652198
 C                 -3.39793834    1.74823990    1.09700021
 C                 -4.19286063    1.86742413   -0.06603842
 C                 -3.74592456    1.17695517   -1.21043327
 C                 -2.57074413    0.42520134   -1.19065134
 H                 -2.28290512   -0.11021310   -2.08914328
 H                 -4.31966130    1.19610630   -2.12911862
 N                 -5.33527779    2.68746735   -0.06334016
 C                 -6.12402168    2.84568855   -1.29004295
 C                 -7.17443093    1.73971508   -1.42456009
 H                 -7.81711199    1.91116382   -2.29348223
 H                 -6.68364200    0.75958934   -1.53649616
 O                 -8.03175700    1.73017487   -0.28104767
 C                 -7.29147959    1.55213820    0.92638095
 C                 -6.23955964    2.65251862    1.09832080
 H                 -5.68412493    2.49735777    2.02337488
 H                 -6.74017959    3.62587862    1.16943631
 H                 -8.01952677    1.57724825    1.74321211
 H                 -6.79477601    0.56738122    0.92591460
 H                 -5.47033871    2.89106153   -2.16349702
 H                 -6.64306509    3.80997987   -1.22168183
 H                 -3.67707374    2.27370576    2.00386111
 H                 -1.67222033    0.91058991    2.03005589
 C                  0.64699433   -0.07356141    0.75090746
 C                  1.69267067   -0.94480357    1.08263611
 C                  2.89012173   -0.49231516    1.61756386
 C                  3.11438738    0.88338052    1.85601443
 C                  2.06314297    1.76082918    1.51173666
 C                  0.87166617    1.28991417    0.96694498
 H                  0.10883310    2.01436611    0.70244135
 H                  2.16256050    2.82826038    1.67029323
 N                  4.29567377    1.35595227    2.45149051
 C                  5.43059631    0.43904850    2.62385506
 C                  6.23033277    0.32493233    1.32363590
 H                  7.11805406   -0.30080904    1.45591646
 H                  5.60263676   -0.11238003    0.53229403
 O                  6.70381527    1.61437534    0.91777402
 C                  5.63504105    2.55561789    0.77003926
 C                  4.81984111    2.67569672    2.06005792
 H                  4.01779458    3.40335566    1.93797458
 H                  5.46402154    3.03276757    2.87184029
 H                  6.10140337    3.51003075    0.50715423
 H                  4.97154003    2.24590884   -0.04972680
 H                  5.09750026   -0.53647417    2.98128665
 H                  6.07634693    0.86241808    3.40181736
 H                  3.66127160   -1.22444777    1.81901734
 H                  1.58029858   -2.00806019    0.89389678
 C                 -1.11013139   -1.93179503    0.64672206
 C                 -1.02490881   -2.17168683    2.02247198
 C                 -1.60439909   -3.30876699    2.58894827
 C                 -2.29114973   -4.24196466    1.80428771
 C                 -2.38371973   -3.99147060    0.42755808
 C                 -1.81503358   -2.85414439   -0.14056465
 H                 -1.91923702   -2.67929620   -1.20543389
 H                 -2.91268792   -4.69685763   -0.20980869
 C                 -2.93433290   -5.46508167    2.41436579
 H                 -2.55577133   -5.65659151    3.42351482
 H                 -4.02319188   -5.34415775    2.48710575
 H                 -2.75096662   -6.35806941    1.80591198
 H                 -1.51504546   -3.47211702    3.66060063
 H                 -0.49579419   -1.47162875    2.66073896
 O                 -0.16065661   -1.00732690   -1.32955941
 C                  0.41502046    0.02268346   -2.15241370
 H                 -0.00587057    0.99569342   -1.88042281
 H                  0.06028840   -0.20913311   -3.16397736
 C                  1.92911152    0.09986361   -2.15057774
 C                  2.74118154   -1.03896430   -2.14435592
 C                  4.13084797   -0.92001211   -2.22287231
 C                  4.75291784    0.33045422   -2.33021134
 C                  3.93053042    1.46635549   -2.35451058
 C                  2.54505400    1.35353554   -2.25234135
 H                  1.93402325    2.25341565   -2.25174307
 H                  4.38299470    2.45176797   -2.44374594
 C                  6.25629590    0.46756747   -2.39980088
 H                  6.55811283    1.10572115   -3.23907384
 H                  6.65380418    0.92579185   -1.48560310
 H                  6.74152425   -0.50607307   -2.52391180
 H                  4.74273266   -1.81943782   -2.20590856
 H                  2.29397505   -2.02489980   -2.06889532
 C                  0.17884311   -3.36120923   -3.51532420
 H                  0.35071497   -4.28591258   -4.07488802
 H                 -0.88789164   -3.10240185   -3.59549111
 H                  0.76410739   -2.55899252   -3.99157028
 O                  0.57564174   -3.58974450   -2.16987682
 H                  0.34261818   -2.77516153   -1.68087485

