%nprocshared=8
%mem=22GB
#p opt freq=noraman b3lyp 6-31G(d) scrf=(solvent=ethanol,pcm) nosymm empiricaldispersion=gd3 scf=maxcyc=512

Opt freq

0 1
 C                 -0.08182034    0.13246465   -0.79095829
 C                 -1.39533877   -0.52392598   -0.36693080
 C                 -2.53205042   -0.40481109   -1.20564907
 C                 -1.60757294   -1.09234260    0.90959855
 C                 -3.79691439   -0.85476869   -0.81332425
 H                 -2.42335871    0.06809029   -2.18713366
 C                 -2.86892132   -1.55266203    1.32063077
 H                 -0.77118721   -1.18491066    1.60845543
 C                 -4.00802679   -1.44866679    0.46986944
 H                 -4.63370199   -0.70698120   -1.50052799
 H                 -2.94927175   -2.01093135    2.30899843
 C                  1.18929016   -0.43552462   -0.12313714
 C                  2.27900379    0.40978450    0.17973836
 C                  1.38500068   -1.82600221    0.05636873
 C                  3.49776982   -0.09354272    0.65732140
 H                  2.17103932    1.48691636    0.01919577
 C                  2.59543744   -2.34567667    0.53954092
 H                  0.57774496   -2.52728127   -0.18064597
 C                  3.69620556   -1.49188387    0.85061521
 H                  4.31143419    0.61280119    0.84301945
 H                  2.66643197   -3.42469358    0.69272476
 C                  0.13983535    0.07208001   -2.31759019
 C                  0.69239140    1.17492778   -3.01276850
 C                 -0.09729311   -1.12139432   -3.03202075
 C                  0.98625789    1.08465597   -4.38397074
 H                  0.88140986    2.10247082   -2.46798375
 C                  0.20078817   -1.20660853   -4.40522852
 H                 -0.52079010   -1.99064032   -2.51837039
 C                  0.74519114   -0.10845116   -5.10897249
 H                  1.41085888    1.95314847   -4.90100712
 H                  0.00509590   -2.14287526   -4.94090111
 N                  4.92250751   -1.99773621    1.30798003
 C                  5.82259843   -1.22354590    2.18990371
 C                  5.22602095   -3.44222031    1.33235982
 C                  7.28689088   -1.47476460    1.81447231
 H                  5.66865548   -1.53898621    3.24584140
 H                  5.59763307   -0.14970355    2.12727030
 C                  6.70705069   -3.66712304    0.98671778
 H                  5.00351889   -3.87663316    2.33137293
 H                  4.61609193   -3.97128312    0.58431185
 H                  7.96912153   -0.98657793    2.52767359
 H                  7.49297560   -1.10795666    0.78805759
 O                  7.59519630   -2.91957268    1.89864947
 H                  6.98301442   -4.72647271    1.10711444
 H                  6.89730660   -3.34790683   -0.05839656
 N                 -5.27888922   -1.87019415    0.87798948
 C                 -6.30944730   -2.33684138   -0.07733041
 C                 -5.55619135   -2.30837275    2.26087293
 C                 -7.70402927   -1.88774289    0.37239764
 H                 -6.29002607   -3.44782933   -0.12595120
 H                 -6.10415599   -1.95519406   -1.08705983
 C                 -6.97389324   -1.87679703    2.66997245
 H                 -5.46063086   -3.41232702    2.35205399
 H                 -4.83959283   -1.84260540    2.95425829
 H                 -8.48682026   -2.31528542   -0.27296239
 H                 -7.77480067   -0.78067651    0.36447663
 O                 -7.98940416   -2.39401599    1.73196252
 H                 -7.23931338   -2.29265153    3.65452427
 H                 -7.03460905   -0.76951124    2.70457323
 O                 -0.16821562    1.62348353   -0.51212444
 C                 -0.34416775    1.97935439    0.92172628
 H                 -1.35552123    1.67210360    1.24786008
 H                  0.40252844    1.43932750    1.53332645
 C                 -0.14885119    3.47187312    1.03152027
 C                  1.06428651    4.01326959    1.51034931
 C                 -1.16972318    4.36487304    0.62663950
 C                  1.25102776    5.40652025    1.59181271
 H                  1.86899698    3.33763221    1.82233379
 C                 -0.98100387    5.75464364    0.70497482
 H                 -2.11659665    3.96476177    0.24773867
 C                  0.23301228    6.30178529    1.19170701
 H                  2.20040302    5.80439761    1.96786544
 H                 -1.78484552    6.42903786    0.38802270
 C                  0.42001439    7.80298237    1.29997619
 H                  0.05362616    8.32424656    0.39673616
 H                 -0.14195308    8.21718783    2.15992214
 H                  1.48214460    8.06755372    1.44074517
 C                  1.04170942   -0.19851465   -6.59382593
 H                  0.31529219    0.39008955   -7.18758291
 H                  2.04608781    0.19655569   -6.83464344
 H                  0.99259857   -1.24223777   -6.94926776


