%nprocshared=24
%mem=41GB
#p opt freq=noraman b3lyp 6-31g(d) scrf=(solvent=methylpropanoate,pcm) nosymm empiricaldispersion=gd3 scf=maxcyc=512

Opt freq

0 1
 C                 -1.20110442   -0.00291515   -0.35830029
 C                 -0.44335908    1.34099086   -0.26619305
 C                 -0.38517234    2.06026446    0.93657606
 C                  0.36200029    3.22868934    1.05869427
 C                  1.09168255    3.73382082   -0.03089226
 C                  1.05406996    3.01018332   -1.23586855
 C                  0.30973967    1.83940708   -1.34083559
 H                  0.34496935    1.30442947   -2.28461568
 H                  1.61636389    3.36803191   -2.09518431
 H                  0.37797615    3.75929991    2.00785788
 H                 -0.92619260    1.69980424    1.80463768
 C                 -2.35486798   -0.02294442    0.67328339
 C                 -2.47022417   -1.00859610    1.65856256
 C                 -3.54115241   -1.00146042    2.55780846
 C                 -4.51743814   -0.00908341    2.48674727
 C                 -4.40805148    0.98964345    1.51471569
 C                 -3.33492313    0.98492143    0.62624841
 H                 -3.25392798    1.77764466   -0.11062445
 H                 -5.15348586    1.77781927    1.45230307
 H                 -3.60772288   -1.77986770    3.31314467
 H                 -1.72550306   -1.79221313    1.72746292
 C                 -1.89835321   -0.06725160   -1.81673315
 H                 -2.08564823    0.96473290   -2.12142352
 C                 -1.05552025   -0.66447161   -2.85465058
 N                 -0.40542284   -1.11209768   -3.70599739
 C                 -3.26849149   -0.77186868   -1.83504729
 O                 -3.46835476   -1.94689003   -1.61823523
 O                 -4.22689592    0.11382687   -2.13253414
 C                 -5.58091056   -0.38773979   -2.07071744
 H                 -5.70578079   -1.23074499   -2.75370278
 H                 -6.21186694    0.44922305   -2.36671062
 H                 -5.80808934   -0.70204541   -1.04884252
 C                 -0.21690345   -1.17413467   -0.15218190
 C                  1.03776647   -0.97731457    0.44185072
 C                  1.91693738   -2.03378105    0.66868372
 C                  1.57477642   -3.34648445    0.30686634
 C                  0.31525105   -3.55511044   -0.28257802
 C                 -0.55544717   -2.49346768   -0.50102896
 H                 -1.52112579   -2.70106148   -0.94714422
 H                  0.01810019   -4.56081503   -0.57139087
 H                  2.88322179   -1.83837668    1.12835113
 H                  1.34955200    0.01903245    0.73206207
 N                  1.81864709    5.00781956    0.06580202
 C                  2.21849597    5.82837950   -1.08836441
 C                  2.24006500    5.62725623    1.32181004
 C                  3.71975595    6.09350989   -1.04629470
 H                  1.67953642    6.79190791   -1.07865704
 H                  1.97198607    5.31606456   -2.02002622
 C                  3.74194605    5.90650431    1.28231958
 H                  1.69731029    6.57042215    1.51228640
 H                  2.03480142    4.94273855    2.15058840
 H                  4.00795514    6.77204243   -1.85452218
 H                  4.26577937    5.14349280   -1.16707502
 O                  4.09786510    6.72456746    0.17320766
 H                  4.04813938    6.44650855    2.18298214
 H                  4.28980314    4.95099371    1.23830320
 N                  2.47281785   -4.47409973    0.59479928
 C                  3.64963817   -4.40162920    1.47521956
 C                  2.29561940   -5.82571157    0.06508508
 C                  4.88638618   -4.90319124    0.73715765
 H                  3.49137182   -5.01723490    2.37795984
 H                  3.81829228   -3.37242671    1.79697331
 C                  3.58132023   -6.28471736   -0.62155364
 H                  2.03003481   -6.54323508    0.86198577
 H                  1.48823721   -5.82279772   -0.67362777
 H                  5.74632086   -4.93048122    1.41277918
 H                  5.11461075   -4.22657782   -0.10270528
 O                  4.69820007   -6.23155945    0.25923497
 H                  3.48449596   -7.32522879   -0.94483834
 H                  3.76758216   -5.65434567   -1.50643972
 C                 -5.69953031   -0.00661641    3.47378931
 H                 -6.23235569   -0.93111840    3.39445958
 H                 -5.33072850    0.10800319    4.47166083
 H                 -6.35683021    0.80498008    3.24104916


