%nprocshared=24
%mem=41GB
#p opt=(calcfc,maxstep=6) freq=noraman b3lyp 6-31g(d) scrf=(solvent=ethanol,pcm) nosymm empiricaldispersion=gd3 scf=maxcyc=512

Opt calcfc freq

-1 1
 C                 -0.03903600    0.26380700   -0.02525000
 C                 -1.17483200   -0.54055600    0.07146000
 N                 -2.15116400   -1.19965300    0.14547500
 C                  1.22027300   -0.33647600   -0.07624600
 C                 -0.15764400    1.77994200    0.00018000
 H                  0.10673400    2.22791600    0.97255200
 H                  0.48878600    2.25154000   -0.75343400
 H                 -1.18730300    2.08339500   -0.22294700
 N                  2.29969700   -0.81002300   -0.12746900


