%nprocshared=24
%mem=41GB
#p b3lyp opt freq=noraman 6-31G(d) scrf=(solvent=methylbutanoate,pcm) nosymm empiricaldispersion=gd3 scf=maxcyc=512

Opt freq

0 1
 C                 -0.34998620   -0.18064972   -1.50092036
 C                 -1.76383299   -0.10117586   -0.91110084
 C                 -2.72260433    0.70485583   -1.54851893
 C                 -2.11427768   -0.65076469    0.32399635
 C                 -3.97617889    0.92256601   -0.99661951
 H                 -2.47301281    1.18338637   -2.49069120
 C                 -3.37862707   -0.45338890    0.88451255
 H                 -1.39856720   -1.25658116    0.86943647
 C                 -4.34272644    0.33798385    0.23588378
 H                 -4.67221682    1.57634839   -1.51250616
 H                 -3.60279921   -0.93386570    1.82960236
 C                  0.50748549   -1.34649262   -0.96862550
 C                  1.87366800   -1.15923105   -0.71525900
 C                  0.00414972   -2.64526292   -0.84203747
 C                  2.69201268   -2.21348309   -0.32703803
 H                  2.30465290   -0.17197015   -0.83983138
 C                  0.81344737   -3.70995634   -0.44332332
 H                 -1.04506729   -2.84026620   -1.04221223
 C                  2.18091233   -3.51786275   -0.17368186
 H                  3.74960110   -2.02647859   -0.16830606
 H                  0.36092738   -4.68854807   -0.33298174
 N                  3.04489661   -4.57274316    0.19282935
 C                  3.87113440   -4.36421457    1.39277864
 C                  2.51351386   -5.93508910    0.15425355
 H                  3.25039723   -4.43421022    2.30339532
 H                  4.32468667   -3.37164871    1.37189689
 H                  1.79437654   -6.11634024    0.97312798
 H                  1.99508375   -6.09687243   -0.79584785
 N                 -5.61304043    0.59890484    0.78696310
 C                 -6.77646615    0.41062250   -0.09474711
 C                 -5.88944751    0.10255091    2.13520746
 H                 -6.96984560   -0.66532244   -0.24816551
 H                 -6.58888335    0.86005644   -1.07127791
 H                 -6.00749841   -0.99553523    2.14684299
 H                 -5.05713523    0.36244489    2.79618159
 O                  0.32084494    1.07394261   -1.25149919
 C                  0.33182122    1.53229461    0.10811488
 H                 -0.64412235    1.97114902    0.35371833
 H                  0.50479611    0.69784961    0.79836418
 C                  1.43318612    2.55219918    0.22563110
 C                  2.63984432    2.24466445    0.86206692
 C                  1.28402604    3.82271760   -0.34634332
 C                  3.66949966    3.18580589    0.93284645
 H                  2.77751731    1.25996497    1.30282191
 C                  2.31376502    4.75882795   -0.27914574
 H                  0.35432648    4.07416020   -0.85154648
 C                  3.52413427    4.45777168    0.36542069
 H                  4.59922287    2.92677723    1.43432902
 H                  2.17953004    5.73946596   -0.73053105
 C                  4.62377623    5.48925208    0.46385756
 H                  4.70789108    6.07338537   -0.45930498
 H                  4.42624030    6.19938756    1.27774878
 H                  5.59433777    5.02364822    0.66347940
 H                 -7.64276122    0.86566753    0.33811183
 H                 -6.77920545    0.55981723    2.51486299
 H                  4.64504482   -5.10179206    1.43684778
 H                  3.31730046   -6.63740974    0.22890480
 H                 -0.36794753   -0.27858640   -2.56627748


