%nprocshared=24
%mem=41GB
#p b3lyp opt freq=noraman 6-31G(d) scrf=(solvent=methylbutanoate,pcm) nosymm empiricaldispersion=gd3 scf=maxcyc=512

Opt freq

0 1
 C                 -1.21526465   -0.02803826    0.88500370
 C                 -0.46356915    1.28235555    0.55945281
 C                  0.26223317    1.96862641    1.53857770
 C                  1.00132017    3.11537502    1.24317995
 C                  1.05955235    3.62364094   -0.06635549
 C                  0.34981100    2.91851482   -1.06008914
 C                 -0.38533368    1.78141021   -0.75171844
 H                 -0.88044654    1.26639539   -1.56869968
 H                  0.39790154    3.24524010   -2.09385877
 H                  1.51731887    3.61585421    2.05403432
 H                  0.25161638    1.61454547    2.56354738
 C                 -2.59706348   -0.01414813    0.04162164
 C                 -2.48668045   -0.60349008   -1.29420608
 N                 -2.42581481   -1.04679720   -2.36548206
 C                 -0.33515899   -1.23914159    0.50866482
 C                  1.05266448   -1.11123624    0.34395000
 C                  1.85971246   -2.20461718    0.04884012
 C                  1.32077588   -3.49866858   -0.08926569
 C                 -0.06933861   -3.63236760    0.08523647
 C                 -0.86950755   -2.52805442    0.37395083
 H                 -1.93130670   -2.68806475    0.52085871
 H                 -0.54437108   -4.60393374    0.01529625
 H                  2.92153262   -2.04045513   -0.10420789
 H                  1.52246636   -0.13870340    0.43166058
 N                  1.82049649    4.75711319   -0.41502729
 C                  1.13939803    5.79831105   -1.20190612
 C                  2.67375325    5.35030099    0.61514968
 H                  0.43071814    6.35617646   -0.56533347
 H                  0.57294942    5.34647391   -2.01797036
 H                  2.07831482    5.87011846    1.38660262
 H                  3.25334609    4.56236369    1.10558527
 N                  2.15497003   -4.58291649   -0.42740394
 C                  3.38458148   -4.75169338    0.36357314
 C                  1.52330144   -5.87402962   -0.70047747
 H                  3.14223563   -5.13711433    1.36931697
 H                  3.89189413   -3.79324885    0.48525770
 H                  1.13730928   -6.34101475    0.22302862
 H                  0.68290847   -5.73002817   -1.38609558
 H                  3.35371227    6.04354417    0.16573937
 H                  1.85731602    6.47899574   -1.60953599
 H                 -1.49311142   -0.04258597    1.91819755
 H                  2.22911329   -6.53253757   -1.16210167
 H                  4.04593743   -5.43568919   -0.12597566
 C                 -3.78653003   -0.66997697    0.76733359
 N                 -4.67214195   -1.15827136    1.30765912
 C                 -2.98059823    1.46382557   -0.15861529
 H                 -2.67906977    2.02975503    0.69795020
 H                 -2.48894773    1.84510496   -1.02913571
 H                 -4.04025907    1.54352010   -0.28378594


