AnalyticalFreq
end

NumericalQuality Good

QTAIM
    Enabled Yes
End

Relativistic Scalar ZORA

SOLVATION
  Surf Delley
  Solv name=Water cav0=0.0 cav1=0.0067639
  Charged method=CONJ
  C-Mat POT
  SCF VAR ALL
  CSMRSP
  Radii
    H=1.30
    O=1.72
    Ta=2.025
  SubEnd
end

ScanFreq -1000 0

XC
  GGA PBE
end

atoms
      1         O     -6.593820     -1.605068     -2.979544
      2        Ta     -0.956639     -3.642473     -0.418906
      3         O     -8.015996     -0.079862     -1.003621
      4        Ta     -7.380418     -3.452934     -2.490870
      5         O     -4.552965     -2.445430      1.339922
      6         O     -2.963516     -4.107134     -0.526523
      7         O     -8.208511     -1.014612      1.560853
      8         O     -5.599775      1.041175     -2.222213
      9         O      0.215080     -2.645044     -1.390704
     10         O     -3.092112     -0.268191      2.472801
     11         O     -0.707531     -5.365238     -1.522521
     12         O     -7.759060     -4.140533     -4.114026
     13         O     -1.829805     -1.693359      0.179735
     14         O     -7.870991     -4.949170     -1.251443
     15         O     -5.579869     -0.073900      0.657159
     16        Ta     -3.641331     -0.526737      0.532957
     17        Ta     -6.419907     -1.720319      1.942496
     18         O     -4.320232     -1.504548     -1.160175
     19         O     -8.290420     -6.124837      1.462314
     20        Ta     -6.170575     -0.485792     -1.463699
     21         O     -9.047228     -2.491552     -1.970342
     22         H     -1.185881     -1.067381     -0.203612
     23         H     -2.482889      0.494065      2.523824
     24         O     -7.050649     -3.515960      2.327040
     25         O     -9.297517     -3.431957      0.656934
     26        Ta     -4.772241     -3.525980     -0.428592
     27         O     -6.086003     -1.044686      3.574694
     28         O     -2.887531      0.959331     -0.118232
     29         O     -5.408148     -3.973640     -2.205823
     30         O    -10.752379     -0.914157     -0.060482
     31         O     -0.203314     -4.084886      1.162888
     32         O     -5.652673     -4.973441      0.452379
     33        Ta     -7.703270     -4.599903      0.704000
     34         O     -6.746628     -2.532461     -0.308532
     35        Ta     -9.092979     -1.604496     -0.171722
end

charge -8

geometry
end

