%nprocshared=12
%mem=20GB
#p b3lyp gen EmpiricalDispersion=GD3 scrf=(smd,solvent=n,n-dimethylacetamide) scf=xqc nosymm integral(ultrafine)

ar25_sp

0 1
 C	-1.007130000	 0.701202000	-0.002756000
 C	 0.389975000	 0.701303000	-0.002559000
 C	 1.091765000	 1.910008000	-0.000275000
 C	 0.390107000	 3.118813000	 0.001852000
 C	-1.006975000	 3.119087000	 0.001671000
 C	-1.719030000	 1.910173000	-0.000645000
 H	-1.551994000	-0.239241000	-0.004539000
 H	 0.929185000	-0.242455000	-0.004205000
 H	 2.178634000	 1.909964000	-0.000136000
 H	 0.929463000	 4.062489000	 0.003628000
 H	-1.551760000	 4.059574000	 0.003313000
 C	-3.212960000	 1.910300000	-0.000826000
 C	-3.927411000	 1.913928000	 1.205608000
 C	-3.927163000	 1.906815000	-1.207372000
 C	-5.324556000	 1.914114000	 1.217117000
 H	-3.389851000	 1.916650000	 2.149638000
 C	-5.324331000	 1.906913000	-1.219159000
 H	-3.389454000	 1.903995000	-2.151318000
 C	-5.996732000	 1.910579000	-0.001097000
 H	-5.865460000	 1.916921000	 2.157065000
 H	-5.865017000	 1.904218000	-2.159232000
 Br	-7.968696000	 1.910786000	-0.001261000

-Br -N -C -H -O 0
cc-pVTZ
****

