%nproc=12
%mem=20GB
%chk=diazo.chk
#p opt b3lyp/gen freq pseudo=read EmpiricalDispersion=GD3BJ scrf=(pcm,solvent=chlorobenzene) pop=(orbitals=20) optcyc=300 nosymm

Title Card Required

0 1
 C                  4.07745849   -2.00172575    0.05596589
 Br                 2.16745849   -2.00172575    0.05596589
 C                  4.84481566   -3.33692472    0.05337686
 O                  4.21777523   -4.42797301    0.05126125
 C                  6.38481566   -3.33692472    0.05337686
 C                  7.08244141   -3.33837690    1.26107630
 C                  7.08238232   -3.33507716   -1.15518174
 C                  8.47760117   -3.33918117    1.26097411
 H                  6.53300203   -3.34020329    2.21362805
 C                  8.47720736   -3.33540230   -1.15520550
 H                  6.53211318   -3.33387315   -2.10728403
 C                  9.17489557   -3.33785091    0.05294808
 H                  9.02742910   -3.34077607    2.21325008
 H                  9.02726054   -3.33393847   -2.10752560
 H                 10.27449947   -3.33830464    0.05268469
 N                  4.51260375   -0.90583041    0.33730994
 N                  4.98561743    0.28544334    0.64314481

-N C O Br H 0
cc-pVDZ
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