%nproc=12
%mem=20GB
%chk=C_09_noRh.chk
#p opt b3lyp/gen freq pseudo=read EmpiricalDispersion=GD3BJ scrf=(pcm,solvent=chlorobenzene) pop=(orbitals=20) optcyc=300 nosymm

Title Card Required

0 1
 C                  1.27337300   -3.85517800   -1.89133600
 C                  2.31825600   -4.41048900   -1.12588800
 C                  1.97558100   -4.28159900    0.33107900
 C                  0.59365200   -3.61245000    0.30112700
 N                  0.18509300   -3.50032400   -1.07920600
 H                 -0.29347400   -2.63367000   -1.31730300
 C                  1.77828600   -2.81228700    0.76195100
 C                  2.13067100   -1.52621000    0.00918100
 Br                 1.80971500   -2.40149000    2.67286100
 C                  3.53784000   -1.04816700   -0.09800900
 O                  1.20693400   -0.83737100   -0.39459600
 C                  3.77565700    0.31979600    0.12056600
 C                  4.60518300   -1.88593900   -0.45234100
 C                  5.06937000    0.83084000    0.03377800
 H                  2.93528000    0.96654500    0.37570800
 C                  5.89650200   -1.36617700   -0.56272300
 H                  4.42320700   -2.93086600   -0.68815600
 C                  6.13339600   -0.01251000   -0.30727700
 H                  5.25011100    1.88961700    0.22869700
 H                  6.71861100   -2.02261700   -0.85365300
 H                  7.14629100    0.38849600   -0.38081700
 C                  2.33113000   -5.41438900    1.25294300
 C                  3.57144400   -5.42287600    1.97502800
 C                  1.48078100   -6.51863200    1.31395900
 C                  3.90069200   -6.54865700    2.80196000
 C                  1.82591500   -7.61604700    2.15032000
 C                  2.99000200   -7.63351000    2.87988700
 H                  1.14265100   -8.46708900    2.19696100
 H                  3.23687300   -8.48954000    3.51214600
 C                  0.20283900   -6.62078100    0.51553300
 H                 -0.62669600   -6.08775200    1.00900800
 H                  0.30080600   -6.20169700   -0.49433300
 H                 -0.09982200   -7.67326000    0.41988400
 H                 -0.18144600   -3.85201600    1.02723700
 C                  1.37588000   -3.77748700   -3.28233000
 C                  3.42974500   -4.97858700   -1.73915600
 H                  4.21537600   -5.43935300   -1.13689500
 H                  0.57900500   -3.32975700   -3.87868800
 C                  3.53057800   -4.92262300   -3.13694100
 C                  2.51900400   -4.31261200   -3.89068000
 H                  2.61308200   -4.26390100   -4.97760200
 H                  4.40199000   -5.34791600   -3.63728700
 C                  4.51685100   -4.36275100    1.89980700
 C                  5.13427700   -6.56489500    3.51058000
 H                  5.36188700   -7.43070000    4.13698500
 H                  4.29164000   -3.49245100    1.29505600
 C                  6.02699100   -5.52054100    3.40662500
 C                  5.71064500   -4.40907700    2.58718000
 H                  6.97261600   -5.54565900    3.95178300
 H                  6.41245500   -3.57680700    2.50180200

-C H O N Br 0
cc-pVDZ
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