%nproc=24
%mem=120GB
%chk=TS1_09_backward.chk
#p opt b3lyp/gen freq pseudo=read EmpiricalDispersion=GD3BJ scrf=(pcm,solvent=chlorobenzene) pop=(orbitals=20) optcyc=300 nosymm

Title Card Required

0 1
 C                 -0.32906000   -4.08939200   -2.29186200
 C                  0.73931400   -4.99262600   -1.94159500
 C                  1.03210100   -4.80067000   -0.63651300
 C                  0.50229900   -3.40827600   -0.28784200
 N                 -0.56751000   -3.24088700   -1.27277600
 H                 -0.92955300   -2.29116300   -1.46120600
 C                  1.70470300   -2.26446300   -0.41935000
 Rh                 0.68183900   -0.08400400   -0.31689700
 C                  2.32988200   -2.21403800   -1.75458600
 Br                 2.83089000   -2.62304800    1.14565900
 Rh                -0.39720400    2.04061800    0.08114500
 C                  3.74836100   -1.74861500   -1.91665700
 O                  1.65701600   -2.40921400   -2.81117200
 C                  4.34391400   -0.78419900   -1.09330300
 C                  4.47028500   -2.25249000   -3.01109900
 C                  5.64086600   -0.34305700   -1.35201700
 H                  3.78039600   -0.34754300   -0.26499500
 C                  5.77469700   -1.82357200   -3.25774700
 H                  3.98646300   -2.97277100   -3.67010400
 C                  6.36848800   -0.86475900   -2.42585400
 H                  6.08480800    0.42273100   -0.71194400
 H                  6.32961500   -2.23079400   -4.10563400
 H                  7.38642300   -0.51942000   -2.62556200
 O                 -1.87030900    1.48897100   -1.26440600
 C                 -1.81599700    0.35339000   -1.80566100
 O                 -0.88919100   -0.51467600   -1.61678800
 C                 -2.92547300   -0.05137100   -2.73746300
 H                 -2.49767500   -0.48737500   -3.65748400
 H                 -3.53137900   -0.82970900   -2.25246800
 H                 -3.56323400    0.80670700   -2.97929500
 O                  1.11028300    2.50473700    1.39582400
 C                  2.06259400    1.67505900    1.55338200
 O                  2.14181900    0.53278400    0.99497300
 C                  3.20350900    2.07625500    2.44903300
 H                  3.59365200    1.19723800    2.97846600
 H                  4.01179100    2.48257400    1.81920800
 H                  2.88491000    2.85162300    3.15643500
 O                  1.70817300    0.82819900   -1.85822700
 C                  1.51741700    2.06473100   -2.09189700
 O                  0.71580800    2.82854200   -1.45952400
 C                  2.30440400    2.65690400   -3.23026600
 H                  2.27262900    3.75240200   -3.19676000
 H                  3.34031100    2.29304000   -3.18925800
 H                  1.86555500    2.30868200   -4.17884200
 O                 -0.42877500   -0.86584200    1.23739600
 C                 -1.24017500   -0.10238300    1.86706100
 O                 -1.44672100    1.12081100    1.61295200
 C                 -1.99315700   -0.72206600    3.01416900
 H                 -1.29091400   -0.88373600    3.84742000
 H                 -2.80610200   -0.06568300    3.34599700
 H                 -2.38561300   -1.70370800    2.71977100
 C                  1.92993700   -5.50138100    0.26265700
 C                  3.30304300   -5.83214500   -0.04036600
 C                  1.30452100   -6.02666800    1.40465800
 C                  4.00414800   -6.72204500    0.83545000
 C                  2.02006100   -6.93059800    2.22349500
 C                  3.32968700   -7.26440200    1.95735100
 H                  1.51064800   -7.36641600    3.08831900
 H                  3.86126400   -7.95679100    2.60801800
 C                 -0.13801100   -5.72617800    1.74028500
 H                 -0.21251800   -4.80141400    2.33118600
 H                 -0.76592200   -5.60788000    0.84836600
 H                 -0.56118700   -6.53798900    2.35062300
 H                  0.10800600   -3.28689800    0.72979000
 C                 -0.99992300   -4.23603200   -3.52719700
 C                  1.17626100   -5.99571600   -2.85670100
 C                  3.99898300   -5.27457400   -1.14383000
 C                  5.36119900   -7.04500900    0.55838500
 H                 -1.82177200   -3.57929400   -3.79976700
 H                  1.98780000   -6.66696800   -2.57342600
 H                  3.48834600   -4.56838900   -1.79250400
 H                  5.88626200   -7.72853700    1.23442700
 C                 -0.56526200   -5.24073200   -4.36937700
 C                  0.52003200   -6.11573100   -4.05022500
 C                  5.31720200   -5.59264300   -1.37873200
 C                  6.01246700   -6.49467800   -0.52466600
 H                  0.81517700   -6.88630600   -4.76351000
 H                 -1.06953200   -5.37642300   -5.33494300
 H                  7.05655000   -6.73695800   -0.73093700
 H                  5.83922800   -5.13923700   -2.22431300

-C H O N Br 0
cc-pVDZ
****
Rh     0
lanl2dz
F    1   1.00
      1.3500000              1.0000000
****

Rh     0
lanl2dz











