%chk=sp_sulfonylpentene_b.chk
%mem=120GB
%nprocshared=20
#p b3lyp/Def2TZVPP scrf=(smd,solvent=acetonitrile) pop=full
empiricaldispersion=gd3bj 

Title Card Required

0 2
 C                  3.19004700    0.26539200   -0.15556800
 H                  3.21265700    0.09905000    0.93773700
 H                  2.89266400    1.31519900   -0.28864500
 C                  2.17152900   -0.63128400   -0.77147200
 H                  2.42584800   -1.67675300   -0.93313700
 C                  0.76723300   -0.23382600   -0.94784600
 H                  0.63645300    0.83343000   -1.15719500
 H                  0.23298500   -0.83389900   -1.69104600
 S                 -0.22243300   -0.49663500    0.61868900
 C                 -1.89295000   -0.02184700    0.16714900
 O                  0.26984400    0.45004300    1.64998400
 O                 -0.21635500   -1.94718300    0.93178800
 C                 -2.28756600    1.30840700    0.33175600
 C                 -2.74268400   -0.97988000   -0.39238600
 C                 -3.57363600    1.68151600   -0.06450900
 H                 -1.60814300    2.03280800    0.76891100
 C                 -4.02553800   -0.59253900   -0.78466200
 H                 -2.41212000   -2.00684700   -0.50947600
 C                 -4.43910900    0.73399300   -0.62126500
 H                 -3.89831400    2.71009800    0.06399000
 H                 -4.70087100   -1.32684400   -1.21434400
 H                 -5.43871400    1.02960700   -0.92766800
 C                  4.60993400    0.04403400   -0.70388200
 H                  4.88186700   -1.01285200   -0.57542300
 H                  4.61277200    0.24006200   -1.78471200
 C                  5.64766200    0.93177100   -0.01376300
 H                  5.68387000    0.73024400    1.06494500
 H                  6.65156600    0.76035500   -0.42155900
 H                  5.40896800    1.99518800   -0.14689500


