%chk=Cl_interm_Ph_butene_def2.chk
%mem=120GB
%nprocshared=24
#p opt freq=noraman ub3lyp/def2svp scrf=(smd,solvent=acetonitrile)
pop=full empiricaldispersion=gd3bj gfinput iop(6/7=3) scf=save

Title Card Required

0 2
 C                  0.06267800   -0.41716200   -0.68908700
 H                  0.11492500   -1.17206000   -1.48242000
 H                  0.57472400    0.48020100   -1.05198700
 C                  0.82095700   -0.95370100    0.55903000
 H                  0.28647700   -1.84900300    0.91162800
 H                  0.77812300   -0.20738000    1.36124400
 C                  2.23295000   -1.30915700    0.25465500
 H                  2.41797200   -2.05524400   -0.51669000
 C                  3.35715100   -0.59353300    0.78619400
 H                  3.19371800   -0.09814200    1.74125400
 H                  4.31664800   -1.10075000    0.72350400
 C                 -1.37816400   -0.09762600   -0.37083400
 C                 -2.37150900   -1.08407500   -0.46839600
 C                 -1.74709400    1.18175300    0.07179700
 C                 -3.69934000   -0.80077200   -0.13477400
 H                 -2.10116100   -2.08047800   -0.81223300
 C                 -3.07356400    1.47047300    0.40690700
 H                 -0.98781800    1.95718000    0.15067800
 C                 -4.05517300    0.47897900    0.30476400
 H                 -4.45570300   -1.57708100   -0.22180800
 H                 -3.34065700    2.46931500    0.74342600
 H                 -5.08757000    0.70202000    0.56172600
 Cl                 3.72923400    1.01649200   -0.37822700

