%chk=prod_cf3_a_butene_Ph.chk
%mem=120GB
%nprocshared=24
#p opt freq=noraman b3lyp scrf=(smd,solvent=acetonitrile) pop=full def2svp
empiricaldispersion=gd3bj

Title Card Required

0 2
 C                 -1.82001000    0.74440900   -0.22997200
 C                 -0.48868300    0.64382700   -0.71308200
 C                 -2.42409500    1.97270700    0.24780600
 C                  0.36185500    0.57371800    0.71646900
 H                 -0.26780700   -0.27661900   -1.26155600
 H                 -0.13532500    1.55593800   -1.20731000
 H                 -1.83588300    2.86281600   -0.00015300
 H                 -3.46411900    2.04803000   -0.12381300
 H                 -0.08629700   -0.17875300    1.37548100
 H                  0.26814600    1.56770000    1.16805900
 C                  1.76830500    0.22117600    0.36498000
 C                  2.19367300   -1.11762800    0.40969100
 C                  2.67565900    1.22250100   -0.02295600
 C                  3.51414100   -1.44575000    0.10053500
 H                  1.48319200   -1.89738800    0.69570300
 C                  3.99564300    0.89226800   -0.32998800
 H                  2.34246500    2.26241300   -0.07208200
 C                  4.41674700   -0.44195300   -0.26990700
 H                  3.84195300   -2.48680600    0.14932600
 H                  4.69993700    1.67664000   -0.61705600
 H                  5.45022800   -0.69962500   -0.51404900
 C                 -2.65668100   -0.53678900   -0.09583000
 F                 -1.91243900   -1.63825300   -0.17093400
 F                 -3.32876200   -0.56044500    1.05450600
 F                 -3.53318300   -0.54399500   -1.10674400
 H                 -2.54635500    1.87897500    1.34952100

