%chk=DCE_EDA_Br_butene_Ph.chk
%mem=120GB
%nprocshared=24
#p opt freq=noraman b3lyp scrf=(smd,solvent=DiChloroEthane) pop=full def2svp
empiricaldispersion=gd3bj

Title Card Required

0 1
 C                 -2.03442300    1.09675200    0.77307800
 H                 -2.29206000    1.52051400    1.75748900
 H                 -1.04966600    0.61764200    0.87691400
 C                 -1.93795200    2.24514300   -0.25234200
 H                 -2.92439300    2.74341400   -0.29839300
 H                 -1.74331400    1.83941800   -1.25875800
 C                 -0.90069400    3.26816500    0.10029800
 H                 -0.90827500    3.62046500    1.14034000
 C                  0.00903400    3.77743200   -0.74800600
 H                  0.04259600    3.47252300   -1.79973900
 H                  0.71989600    4.54507500   -0.42786900
 S                  2.91398100   -0.57864300    0.13744900
 O                  3.74816900   -0.77266600   -1.04331900
 O                  3.44216400   -0.67849300    1.49350300
 C                  1.49838200   -1.84886100    0.01690500
 F                  0.90679000   -1.72929000   -1.15873500
 F                  2.03140400   -3.05067000    0.14231000
 F                  0.63279300   -1.62723500    0.99019500
 C                 -3.05611200    0.05911500    0.37736300
 C                 -4.40432300    0.19672200    0.74479700
 C                 -2.68730900   -1.04393300   -0.40993200
 C                 -5.35813600   -0.74219000    0.34027300
 H                 -4.70731300    1.04937000    1.35951600
 C                 -3.63780900   -1.98531400   -0.81616000
 H                 -1.64197500   -1.16759500   -0.70318900
 C                 -4.97776000   -1.83741200   -0.44260000
 H                 -6.40234600   -0.62005800    0.64029200
 H                 -3.33005300   -2.83970200   -1.42495700
 H                 -5.72164600   -2.57364200   -0.75769400
 Br                 1.67416900    1.34889100   -0.07915900

