%nprocshared=24
%mem=120GB
#p opt freq=noraman b3lyp/genecp scrf=(smd,solvent=toluene) nosymm empiricaldispersion=gd3

cinbr_tol

0 1
 C	-2.537827000	 0.605310000	 2.349659000
 H	-2.029997000	 1.220864000	 3.089100000
 H	-3.442198000	 0.151985000	 2.750281000
 C	-2.695595000	 1.227945000	 1.033061000
 C	-3.815375000	 1.071732000	 0.297673000
 H	-4.610228000	 0.451017000	 0.712262000
 H	-1.863492000	 1.829641000	 0.676614000
 Br	-1.204348000	-1.047879000	 2.243902000
 C	-4.108970000	 1.657655000	-1.012520000
 C	-3.171197000	 2.408077000	-1.751488000
 C	-5.387917000	 1.457628000	-1.567213000
 C	-3.507846000	 2.939370000	-2.993075000
 H	-2.172935000	 2.570261000	-1.357195000
 C	-5.724177000	 1.991397000	-2.810634000
 H	-6.120969000	 0.877588000	-1.012370000
 C	-4.785240000	 2.735509000	-3.528274000
 H	-2.771579000	 3.512741000	-3.549216000
 H	-6.716975000	 1.825429000	-3.218959000
 H	-5.042930000	 3.151529000	-4.497949000

-C -H -P -Cl -N -O -F 0
6-31G**
****
-Au -I -Br -Sn 0
SDD
****

-Au 0
SDD
-I -Br -Sn 0
SDD


