%nprocshared=24
%mem=120GB
#p opt freq=noraman b3lyp/genecp scrf=(smd,solvent=toluene) nosymm empiricaldispersion=gd3

oxadcin_tol

0 1
 Au	-0.788508000	 1.870548000	 1.165109000
 P	 1.100350000	 0.497104000	 0.485963000
 C	 1.954423000	 1.219004000	-0.965566000
 H	 2.360810000	 2.197692000	-0.694913000
 H	 2.768649000	 0.568421000	-1.299620000
 H	 1.240023000	 1.352204000	-1.782974000
 C	 2.424741000	 0.220116000	 1.715538000
 H	 2.015420000	-0.302743000	 2.582885000
 H	 3.225236000	-0.377415000	 1.267914000
 H	 2.820457000	 1.180678000	 2.050895000
 C	 0.622092000	-1.186012000	-0.057600000
 H	 1.512452000	-1.767981000	-0.315873000
 H	 0.078518000	-1.690912000	 0.745562000
 H	-0.025211000	-1.119700000	-0.934712000
 C	-1.812259000	 1.461069000	-0.679810000
 H	-2.030854000	 2.459677000	-1.062121000
 H	-1.113917000	 0.944616000	-1.339839000
 C	-3.018128000	 0.672349000	-0.380726000
 C	-3.150536000	-0.649872000	-0.618048000
 H	-2.328405000	-1.174821000	-1.103937000
 H	-3.832352000	 1.218936000	 0.088303000
 C	-2.428806000	 3.055379000	 1.647076000
 C	-2.691483000	 4.254719000	 0.971517000
 C	-3.306748000	 2.647560000	 2.662908000
 C	-3.801198000	 5.038673000	 1.311968000
 H	-2.033937000	 4.589060000	 0.172456000
 C	-4.422209000	 3.423193000	 2.994648000
 H	-3.120299000	 1.725095000	 3.205974000
 C	-4.671541000	 4.622905000	 2.321226000
 H	-3.984455000	 5.970883000	 0.782850000
 H	-5.092886000	 3.090668000	 3.783350000
 H	-5.536862000	 5.226640000	 2.581176000
 Br	 0.311081000	 2.418371000	 3.536427000
 C	-4.322081000	-1.474635000	-0.303942000
 C	-4.405960000	-2.775746000	-0.837370000
 C	-5.378120000	-1.028139000	 0.518727000
 C	-5.505304000	-3.593722000	-0.577074000
 H	-3.599251000	-3.141838000	-1.468157000
 C	-6.474890000	-1.845859000	 0.777834000
 H	-5.334096000	-0.040588000	 0.968479000
 C	-6.547459000	-3.131924000	 0.230122000
 H	-5.547328000	-4.591968000	-1.004146000
 H	-7.275363000	-1.481859000	 1.416218000
 H	-7.404243000	-3.766726000	 0.437137000

-C -H -P -Cl -N -O -F 0
6-31G**
****
-Au -I -Br -Sn 0
SDD
****

-Au 0
SDD
-I -Br -Sn 0
SDD


