%nprocshared=24
%mem=120GB
#p opt=(ts,noeigentest,calcfc) freq=noraman b3lyp/genecp scrf=(smd,solvent=toluene) nosymm empiricaldispersion=gd3

tscinsn2_tol

0 1
 Au	-0.645171000	 1.596983000	 0.916845000
 P	 1.531022000	 0.755351000	 0.362403000
 C	 2.271918000	 1.504460000	-1.134257000
 H	 2.266009000	 2.594374000	-1.044720000
 H	 3.301306000	 1.154577000	-1.262983000
 H	 1.681927000	 1.203869000	-2.006722000
 C	 2.732887000	 1.077658000	 1.710549000
 H	 2.405802000	 0.566021000	 2.620300000
 H	 3.727442000	 0.717699000	 1.428384000
 H	 2.778929000	 2.152207000	 1.909633000
 C	 1.623906000	-1.049372000	 0.064584000
 H	 2.668910000	-1.362705000	-0.026347000
 H	 1.154340000	-1.587525000	 0.892776000
 H	 1.104021000	-1.284836000	-0.870076000
 C	-1.650973000	 0.742395000	-1.119212000
 H	-1.381977000	 1.658932000	-1.634976000
 H	-0.950227000	-0.078178000	-1.223330000
 C	-3.014442000	 0.451035000	-0.892039000
 C	-3.422850000	-0.818043000	-0.567368000
 H	-2.658820000	-1.594384000	-0.530798000
 H	-3.729113000	 1.264284000	-0.956352000
 C	-2.415552000	 2.432974000	 1.593119000
 C	-2.556619000	 3.832420000	 1.672768000
 C	-3.485979000	 1.643110000	 2.053496000
 C	-3.714541000	 4.416018000	 2.202202000
 H	-1.758222000	 4.481913000	 1.320546000
 C	-4.640715000	 2.220024000	 2.589942000
 H	-3.431944000	 0.559985000	 1.974509000
 C	-4.758994000	 3.611750000	 2.662765000
 H	-3.798804000	 5.499057000	 2.250598000
 H	-5.450515000	 1.584279000	 2.939526000
 H	-5.659519000	 4.063867000	 3.069725000
 Br	 0.108975000	-0.734174000	-3.635517000
 C	-4.770565000	-1.243406000	-0.267535000
 C	-5.023260000	-2.624175000	-0.101977000
 C	-5.841309000	-0.332360000	-0.101492000
 C	-6.300701000	-3.081623000	 0.203855000
 H	-4.205363000	-3.329173000	-0.223154000
 C	-7.112906000	-0.794860000	 0.211628000
 H	-5.668338000	 0.734100000	-0.195498000
 C	-7.347915000	-2.168246000	 0.361444000
 H	-6.482265000	-4.145407000	 0.322674000
 H	-7.926156000	-0.087750000	 0.343772000
 H	-8.345118000	-2.522738000	 0.605392000

-C -H -P -Cl -N -O -F 0
6-31G**
****
-Au -I -Br -Sn 0
SDD
****

-Au 0
SDD
-I -Br -Sn 0
SDD


