%nprocshared=24
%mem=120GB
#p opt=(ts,noeigentest,calcfc) freq=noraman b3lyp/genecp scrf=(smd,solvent=toluene) nosymm empiricaldispersion=gd3

tscinredelim_tol

0 1
 Au	-0.146124000	 0.193249000	 1.733338000
 P	 2.047827000	 0.064917000	 0.850183000
 C	 2.182363000	 0.045403000	-0.980939000
 H	 1.774616000	 0.975320000	-1.387355000
 H	 3.227651000	-0.051793000	-1.292414000
 H	 1.609386000	-0.795312000	-1.382197000
 C	 3.120823000	 1.453219000	 1.371710000
 H	 3.143274000	 1.474456000	 2.464250000
 H	 4.134049000	 1.330821000	 0.975896000
 H	 2.700450000	 2.396502000	 1.011422000
 C	 2.944335000	-1.435292000	 1.398167000
 H	 3.973899000	-1.430051000	 1.026503000
 H	 2.942197000	-1.452597000	 2.491404000
 H	 2.427796000	-2.326894000	 1.031239000
 C	-2.096888000	-0.209482000	 0.306907000
 H	-1.658388000	-1.198560000	 0.185669000
 H	-3.157824000	-0.284523000	 0.511553000
 C	-1.746570000	 0.785021000	-0.702764000
 C	-2.546834000	 1.831379000	-1.013886000
 H	-3.497823000	 1.914253000	-0.488526000
 H	-0.779323000	 0.666546000	-1.184988000
 C	-2.168347000	 0.419334000	 2.355849000
 C	-2.706195000	-0.555355000	 3.213826000
 C	-2.621674000	 1.743916000	 2.430729000
 C	-3.636976000	-0.184758000	 4.183670000
 H	-2.385736000	-1.589985000	 3.133401000
 C	-3.547143000	 2.110533000	 3.411003000
 H	-2.261933000	 2.481471000	 1.717715000
 C	-4.055755000	 1.147649000	 4.287135000
 H	-4.037539000	-0.934951000	 4.860148000
 H	-3.880435000	 3.142577000	 3.479718000
 H	-4.786403000	 1.429600000	 5.039812000
 Br	 1.082705000	 0.304312000	 4.448754000
 C	-2.275798000	 2.889265000	-1.988249000
 C	-3.270757000	 3.857580000	-2.230081000
 C	-1.058376000	 2.999902000	-2.693663000
 C	-3.066305000	 4.888711000	-3.145922000
 H	-4.213276000	 3.792335000	-1.692109000
 C	-0.856170000	 4.029382000	-3.608536000
 H	-0.264558000	 2.278473000	-2.525666000
 C	-1.857704000	 4.979498000	-3.840187000
 H	-3.849450000	 5.622219000	-3.315712000
 H	 0.088508000	 4.096017000	-4.141133000
 H	-1.694543000	 5.782404000	-4.553203000

-C -H -P -Cl -N -O -F 0
6-31G**
****
-Au -I -Br -Sn 0
SDD
****

-Au 0
SDD
-I -Br -Sn 0
SDD


