%nprocshared=24
%mem=120GB
%chk=ts2.chk
#p opt=(ts,noeigentest,calcfc) freq=noraman genecp scrf=(smd,solvent=iodomethane) nosymm b3lyp empiricaldispersion=gd3

Title Card Required

0 1
 Au                -0.19472000    1.41906200    1.32904300
 P                  1.93734000    0.79310800    0.41947900
 C                  2.45943600    1.85037500   -0.98537500
 H                  2.48784100    2.89553300   -0.66594100
 H                  3.44921600    1.55320900   -1.34669100
 H                  1.73556700    1.75160400   -1.79940400
 C                  3.33114600    0.86825000    1.60789400
 H                  3.13275800    0.19540300    2.44723900
 H                  4.26724000    0.57423900    1.12129600
 H                  3.42803000    1.88766000    1.99289000
 C                  1.99316200   -0.91241100   -0.25144600
 H                  2.98742900   -1.13729300   -0.65086700
 H                  1.75115800   -1.62450600    0.54181000
 H                  1.25466400   -1.01407600   -1.05152300
 C                 -1.21924700    1.51096800   -0.83163700
 H                 -2.22716100    1.72779400   -0.51534200
 H                 -0.57526500    2.32312100   -1.13843000
 H                 -0.93827500    0.48805200   -1.03774200
 C                 -2.02062900    1.98091700    2.17557400
 H                 -2.80972000    1.25520400    1.95024900
 H                 -1.89895000    2.03311500    3.26699300
 H                 -2.34128600    2.96595100    1.81477000
 I                 -2.16000900    1.52375200   -3.47442800

-C -H -P 0
6-31G**
****
-Au -I 0
SDD
****

-Au 0
SDD
-I 0
SDD 




