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Thermodynamic Stability of Heterodimetallic [LnLn’] Complexes Collection home page

The solid state and solution configuration of the heterodimetallic complexes, (Hpy)[CeEr(HL)3(NO3)(py)(H2O)] (1), (Hpy)[PrSm(HL)3(NO3)(py)(H2O)] (2) and (Hpy)2[LaYb(HL)3(NO3)(H2O)](NO3) (3), where H3L is 6-(3-oxo-3-(2-hydroxyphenyl)propionyl)pyridine-2-carboxylic acid, are analysed experimentally and through DFT calculations. The theoretical study is also extended to the [LaCe], [LaLu] and [CeGd] analogues. The results are consistent with a remarkable selectivity of the metal distribution within the molecule while in the solid state, enhanced by the size difference of both metals. This selectivity is significantly reduced in solution.

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Please use this identifier to cite or link to this collection: DOI: 10.19061/iochem-bd-1-22

This dataset derived results are published in:

Manuscript title: Thermodynamic Stability of Heterodimetallic [LnLn’] Complexes: Synthesis and DFT Studies

DOI: 10.1002/chem.201700095

View as
  • ROOT
    • Ce2
    • CeEr
    • CeGd
    • CeLa
    • Er2
    • ErCe
    • GdCe
    • La2
    • LaCe
    • LaLu
    • LaYb
    • LuLa
    • Pr2
    • PrSm
    • PrYb
    • Sm2
    • SmPr
    • Yb2
    • YbLa
    • YbPr
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