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Our research focuses on the invention of new synthetic methods based on the catalytic use of electrophilic metal complexes of gold and other transition metals. We are also interested in developing new strategies for the synthesis of complex, biologically active molecules as well as large polyarenes of interest in material science.

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4+3 DOI: 10.19061/iochem-bd-1-186

This dataset derived results are published in:

Manuscript title: Assembly of Complex 1,4-Cycloheptadienes by (4+3) Cycloaddition of Rhodium(II) and Gold(I) Non-Acceptor Carbenes

Journal: Angew. Chem. Int. Ed.

DOI: 10.1002/anie.202012092

Cavitands DOI: 10.19061/iochem-bd-1-196

No other publication derived

Enantioselective_Folding_of_Enynes DOI: 10.19061/iochem-bd-1-166

This dataset derived results are published in:

Manuscript title: Enantioselective Folding of Enynes by Gold(I) Catalysts with a Remote C2-Chiral Element

Journal: J. Am. Chem. Soc.

DOI: 10.1021/jacs.9b06326

Ferrocenyl_Chiral_Gold(I)_Complexes DOI: 10.19061/iochem-bd-1-235

This dataset derived results are published in:

Manuscript title: Planar Chiral 1,3-Disubstituted Ferrocenyl Phosphine Gold(I) Catalysts

Journal: ACS Catal.

DOI: 10.1021/acscatal.1c05827

On_the_Structures_of_Au(I)_Intermediates DOI: 10.19061/iochem-bd-1-189

This dataset derived results are published in:

Manuscript title: On the Structure of Intermediates in Enyne Gold(I)‐Catalyzed Cyclizations: Formation of trans‐Fused Bicyclo[5.1.0]octanes as a Case Study

DOI: 10.1002/chem.202004237

Paper DOI: 10.19061/iochem-bd-1-153

This dataset derived results are published in:

Manuscript title: Synthesis of Trienes by Rhodium-Catalyzed Assembly and Disassembly of Non-Acceptor Cyclopropanes

Journal: ACS Catal.

DOI: 10.1021/acscatal.0c00006

Rhodium-Catalysed ortho-Alkynylation of Nitroarenes DOI: 10.19061/iochem-bd-1-158

Computational mechanistic studies on the Rhodium-Catalysed ortho-Alkynylation of Nitroarenes. These results, together with experimental studies, demonstrate that the reaction proceeds via a turnover-limiting electrophilic C–H metalation ortho to the strongly electron-withdrawing nitro group.

This dataset derived results are published in:

Manuscript title: Rhodium-Catalysed ortho-Alkynylation of Nitroarenes

Journal: Chem. Sci.

DOI: 10.1039/D1SC04527J

Waitzacuminone DOI: 10.19061/iochem-bd-1-148

This dataset derived results are published in:

Manuscript title: Acetylene as a Dicarbene Equivalent via Gold(I) Catalysis: Total Synthesis of Waitziacuminone in One Step

Journal: Angew. Chem. Int. Ed.

DOI: 10.1002/ange.201915895

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