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Our research focuses on the invention of new synthetic methods based on the catalytic use of electrophilic metal complexes of gold and other transition metals. We are also interested in developing new strategies for the synthesis of complex, biologically active molecules as well as large polyarenes of interest in material science.

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4+3 DOI: 10.19061/iochem-bd-1-186

This dataset derived results are published in:

Manuscript title: Assembly of Complex 1,4-Cycloheptadienes by (4+3) Cycloaddition of Rhodium(II) and Gold(I) Non-Acceptor Carbenes

Journal: Angew. Chem. Int. Ed.

DOI: 10.1002/anie.202012092

C60mechanochem DOI: 10.19061/iochem-bd-1-304

Solution and mechanochemical reactivity of C60 with MCN

This dataset derived results are published in:

Manuscript title: Understanding the divergence in outcomes between mechanochemical and solution phase reactivity of fullerenes

DOI: 10.1016/j.xcrp.2025.102434

Cavitands DOI: 10.19061/iochem-bd-1-196

No other publication derived

Chiral_Auxiliary_Approach_for_Gold(I)-Catalyzed_Cyclizations DOI: 10.19061/iochem-bd-1-281

This dataset derived results are published in:

Manuscript title: Chiral Auxiliary Approach for Gold(I) Catalyzed Cyclizations

Journal: Angew. Chem. Int. Ed.

DOI: 10.1002/anie.202312874

Chiral_Phosphite_Gold(I)_Complex-Chiral_Counterion DOI: 10.19061/iochem-bd-1-280

This dataset derived results are published in:

Manuscript title: Hydrogen-Bonded Matched Ion Pair Gold(I) Catalysis

Journal: ACS Catal.

DOI: 10.1021/acscatal.3c02638

DFT_and_NEST_Analysis_DFT_Chiral_Ferrocenenylphosphino_Au(I)_Cat DOI: 10.19061/iochem-bd-1-362

This dataset derived results are published in:

Manuscript title: Practical Synthesis of Chiral Ferrocenenylphosphino-Gold(I) 2 Catalysts and NEST Analysis of the Enantioinduction

Journal: ACS Catal.

DOI: 10.1021/acscatal.4c07495

DFT_and_NEST_Analysis_of_the_Chiral_Binding_Pocket DOI: 10.19061/iochem-bd-1-271

This dataset derived results are published in:

Manuscript title: Enantioselective Catalysis with Pyrrolidinyl Gold(I) Complexes: DFT and NEST Analysis of the Chiral Binding Pocket

Journal: JACS

DOI: 10.1021/jacsau.3c00159

Enantioselective_Folding_of_Enynes DOI: 10.19061/iochem-bd-1-166

This dataset derived results are published in:

Manuscript title: Enantioselective Folding of Enynes by Gold(I) Catalysts with a Remote C2-Chiral Element

Journal: J. Am. Chem. Soc.

DOI: 10.1021/jacs.9b06326

FePorphyrinCu_CO DOI: 10.19061/iochem-bd-1-331

Calculations on the CO transfer between a tethered Fe porphyrin complex and a Cu(1 1 1) surface.

This dataset derived results are published in:

Manuscript title: Molecular Hybrid Materials for Selective CO2 Electroreduction to Multicarbon Products

DOI: 10.1002/aenm.202402070

Ferrocenyl_Chiral_Gold(I)_Complexes DOI: 10.19061/iochem-bd-1-235

This dataset derived results are published in:

Manuscript title: Planar Chiral 1,3-Disubstituted Ferrocenyl Phosphine Gold(I) Catalysts

Journal: ACS Catal.

DOI: 10.1021/acscatal.1c05827

Gold_Allenes_Mesoionic DOI: 10.19061/iochem-bd-1-335

DFT study on reactivity of allenes towards sydnones and münchnones.

No other publication derived

Gold_Allenes_Mesoionic

No other publication derived

Gold-Catalyzed_Alkyne_Cyclotrimerization DOI: 10.19061/iochem-bd-1-309

Gold(I)-catalyzed cyclotrimerization of alkynes, full mechanisms and other calculations

No other publication derived

Gold(I)-Catalyzed_1,6-Enyne_Single_Cleavage_Rearrangements DOI: 10.19061/iochem-bd-1-287

This dataset derived results are published in:

Manuscript title: Gold(I)-Catalyzed 1,6-Enyne Single-Cleavage Rearrangements: The Complete Picture

DOI: 10.1021/acsorginorgau.3c00028

Gold(I)-Catalyzed_Cyclizations_Enynes_Allenenes DOI: 10.19061/iochem-bd-1-289

This dataset derived results are published in:

Manuscript title: The Puzzling Structure of the Key Intermediates in Gold(I) Catalyzed Cyclizations of Enynes and Allenenes

Journal: Chem

DOI: 10.1002/cplu.202300502

Gold(I)_HCDC DOI: 10.19061/iochem-bd-1-351

This dataset derived results are published in:

Manuscript title: H-bonded Counterion-Directed Enantioselective Au(I) Catalysis

Journal: J. Am. Chem. Soc.

DOI: 10.1021/jacs.1c11978

HaloenyneAlkoxycyclizations_and_Racemization DOI: 10.19061/iochem-bd-1-307

Enantioselective Cyclizations of Bromoenynes A New Mechanistic Understanding of Gold(I)-Catalyzed Alkoxycyclizations

No other publication derived

On_the_Structures_of_Au(I)_Intermediates DOI: 10.19061/iochem-bd-1-189

This dataset derived results are published in:

Manuscript title: On the Structure of Intermediates in Enyne Gold(I)‐Catalyzed Cyclizations: Formation of trans‐Fused Bicyclo[5.1.0]octanes as a Case Study

DOI: 10.1002/chem.202004237

Paper DOI: 10.19061/iochem-bd-1-153

This dataset derived results are published in:

Manuscript title: Synthesis of Trienes by Rhodium-Catalyzed Assembly and Disassembly of Non-Acceptor Cyclopropanes

Journal: ACS Catal.

DOI: 10.1021/acscatal.0c00006

prova

No other publication derived

Rhodium-Catalysed ortho-Alkynylation of Nitroarenes DOI: 10.19061/iochem-bd-1-158

Computational mechanistic studies on the Rhodium-Catalysed ortho-Alkynylation of Nitroarenes. These results, together with experimental studies, demonstrate that the reaction proceeds via a turnover-limiting electrophilic C–H metalation ortho to the strongly electron-withdrawing nitro group.

This dataset derived results are published in:

Manuscript title: Rhodium-Catalysed ortho-Alkynylation of Nitroarenes

Journal: Chem. Sci.

DOI: 10.1039/D1SC04527J

Silver-free_gold(I)_catalysis DOI: 10.19061/iochem-bd-1-350

This dataset derived results are published in:

Manuscript title: Siver-Free Au(I) Catalysis Enabled by Bifunctional Urea- and Squaramide-Phosphine Ligands via H-bonding

Journal: Chem. Eur. J.

DOI: 10.1002/chem.202101751

TriarylmechanophoreCleavage DOI: 10.19061/iochem-bd-1-341

No other publication derived

vinylidenes

No other publication derived

Waitzacuminone DOI: 10.19061/iochem-bd-1-148

This dataset derived results are published in:

Manuscript title: Acetylene as a Dicarbene Equivalent via Gold(I) Catalysis: Total Synthesis of Waitziacuminone in One Step

Journal: Angew. Chem. Int. Ed.

DOI: 10.1002/ange.201915895

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