Rhodium-Catalysed ortho-Alkynylation of Nitroarenes Collection home page

Computational mechanistic studies on the Rhodium-Catalysed ortho-Alkynylation of Nitroarenes. These results, together with experimental studies, demonstrate that the reaction proceeds via a turnover-limiting electrophilic C–H metalation ortho to the strongly electron-withdrawing nitro group.

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Please use this identifier to cite or link to this collection: DOI: 10.19061/iochem-bd-1-158

This dataset derived results are published in:

Manuscript title: Rhodium-Catalysed ortho-Alkynylation of Nitroarenes

Journal: Chem. Sci.

DOI: 10.1039/D1SC04527J

View as
    • ROOT
      • Paper
        • Outputs_Inputs_CGET
          • 1_NO2
          • 1a
          • 1ae
          • 1ai
          • 1j
          • 1p
          • 1q
          • 1r
          • 1s
          • 1t
          • 1u
          • 2a
          • 2b
          • 2c
          • 2d
          • 2f
          • 3a
          • 3a_Ph
          • 3a_TES
          • 3j
          • AcOH
          • AgBr
          • AgCl
          • AgI
          • AgOAc
          • ICp_star
          • II
            • NBO
          • III
          • III_Br_Cpstar
          • III_CF3_Cpstar
          • III_Cl_Cpstar
          • III_F_Cpstar
          • III_H_CPstar
          • III_H_Cp
          • III_Me_Cpstar
          • III_NO2_Cpstar
          • III_OMe_Cpstar
          • II_Br_Cpstar
          • II_CF3_Cpstar
          • II_Cl_Cpstar
          • II_F_Cpstar
          • II_H_CPstar
          • II_H_Cp
          • II_Me_Cpstar
          • II_NO2_Cpstar
          • II_OMe_Cpstar
          • IV
          • KIE_110
            • 1j_110
            • 1j_d5_110
            • 2_110
            • III_D_Cp_110
            • III_D_Cpstar_II_III
            • III_H_Cp_110
            • III_H_Cpstar_110
            • II_D_Cp_110
            • II_D_Cpstar_110
            • II_H_Cp_110
            • II_H_Cpstar_110
            • I_110
            • I_Cp_star_110
            • TS_D_Cp_II_III_110
            • TS_D_Cpstar_II_III
            • TS_H_Cp_II_III_110
            • TS_H_Cpstar_II_III
          • NBO
          • S1
          • S10
          • S11
          • S12
          • S13
          • S14
          • S15
          • S16
          • S17
          • S18
          • S19
          • S2
          • S20
          • S21
          • S22
          • S23
          • S24
          • S25
          • S26
          • S27
          • S28
          • S29
          • S3
          • S30
          • S31
          • S32
          • S33
          • S34
          • S4
          • S5
          • S6
          • S7
          • S8
          • S9
          • TSCH2
          • TSCH2_4
          • TSCH2_Inter
          • TSCH_4
          • TSCH_Inter
          • TSII_III
            • NBO
          • TSIV_V
            • NBO
          • TSS12_S13
          • TSS14_S15
          • TSS17_S18
          • TSS20_S21
          • TSS22_VII
          • TSS24_S25
          • TSS26_VII
          • TSS28_S29
          • TSS30_S31
          • TSS33_Vprima
          • TSVI_VII
            • NBO
          • TSVIprima_S34
          • TS_Br_Cpstar_II_III
            • NBO
          • TS_CF3_Cpstar_II_III
            • NBO
          • TS_Cl_Cpstar_II_III
            • NBO
          • TS_F_Cpstar_II_III
            • NBO
          • TS_H_Cp_II_III
          • TS_H_Cpstar_II_III
            • NBO
          • TS_Me_Cpstar_II_III
            • NBO
          • TS_NO2_Cpstar_II_III
            • NBO
          • TS_OMe_Cpstar_II_III
            • NBO
          • VI
            • NBO
          • VII
          • VI_prima
            • NBO
          • V_prima
            • NBO
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